Propargyl group: Difference between revisions
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{{Short description|Chemical group (–CH₂C≡CH)}} |
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[[Image:Propargyl.png|thumb|right|Chemical structure of the propargyl group.]] |
[[Image:Propargyl.png|thumb|right|Chemical structure of the propargyl group.]] |
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⚫ | The term '''propargylic''' refers to a [[Saturated and unsaturated compounds|saturated]] position ([[Orbital hybridisation#sp3|''sp''<sup>3</sup>-hybridized]]) on a molecular framework next to an [[alkynyl]] group. The name comes from mix of ''propene'' and ''argentum'', which refers to the typical reaction of the terminal alkynes with [[silver salts]]. |
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The term '''homopropargylic''' designates in the same manner |
The term '''homopropargylic''' designates in the same manner |
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* a saturated position on a molecular framework next to a propargylic group and thus two bonds from an [[alkyne]] moiety |
* a saturated position on a molecular framework next to a propargylic group and thus two bonds from an [[alkyne]] moiety.<ref>{{cite journal|last1=Ferreira|first1=Franck|last2=Denichoux|first2=Aurélien|last3=Chemla|first3=Fabrice|last4=Bejjani|first4=Joseph|title=Highly Diastereoselective Syntheses of Propargylic Acid and Homopropargylic Systems|journal=[[Synlett]]|date=2004|issue=12|pages=2051–2065|doi=10.1055/s-2004-832816}}</ref> |
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* a fragment HC |
* a 3-butynyl fragment, {{chem2|HC\tC\sCH2CH2\s}}, or substituted homologue. |
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==See also== |
==See also== |
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* [[Allyl |
** [[Allyl]] |
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* [[Benzyl#Benzylic position|Benzylic]] |
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* [[ |
** [[Vinyl group]] |
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* [[ |
* [[Ethynyl radical|Ethynyl]] |
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* [[Propargyl chloride]] |
* [[Propargyl chloride]] |
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* [[Propargyl alcohol]] |
* [[Propargyl alcohol]] |
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* [[Propargyl bromide]] |
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* [[Propiolic acid]] |
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==References== |
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{{Reflist}} |
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{{Commonscat}} |
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{{hydrocarbon-stub}} |
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[[Category:Propargyl compounds| ]] |
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[[Category:Functional groups]] |
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[[de:Propargylgruppe]] |
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[[fr: propargylique]] |
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[[ja:プロパルギル基]] |
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[[sv:Propargylgrupp]] |
Latest revision as of 08:27, 3 February 2023
In organic chemistry, the propargyl group is a functional group of 2-propynyl with the structure CH≡C−CH2−. It is an alkyl group derived from propyne (HC≡C−CH3).
The term propargylic refers to a saturated position (sp3-hybridized) on a molecular framework next to an alkynyl group. The name comes from mix of propene and argentum, which refers to the typical reaction of the terminal alkynes with silver salts.
The term homopropargylic designates in the same manner
- a saturated position on a molecular framework next to a propargylic group and thus two bonds from an alkyne moiety.[1]
- a 3-butynyl fragment, HC≡C−CH2CH2−, or substituted homologue.
See also[edit]
References[edit]
- ^ Ferreira, Franck; Denichoux, Aurélien; Chemla, Fabrice; Bejjani, Joseph (2004). "Highly Diastereoselective Syntheses of Propargylic Acid and Homopropargylic Systems". Synlett (12): 2051–2065. doi:10.1055/s-2004-832816.
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