User:Rhenium75/sandbox/tropylium hexafluorophosphate: Difference between revisions
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| Appearance = white solid |
| Appearance = white solid |
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| Density = |
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| MeltingPtC = |
| MeltingPtC = 190-215 |
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| MeltingPt_notes = decomposition |
| MeltingPt_notes = decomposition |
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[[Category:Hexafluorophosphate]] |
[[:Category:Hexafluorophosphate]] |
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[[Category:Carbocations]] |
[[:Category:Carbocations]] |
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[[Category:Non-benzenoid aromatic carbocycles]] |
[[:Category:Non-benzenoid aromatic carbocycles]] |
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Latest revision as of 15:42, 2 April 2020
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| Names | |||
|---|---|---|---|
| Other names
cycloheptatrienyl hexafluorophosphate
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| Identifiers | |||
3D model (JSmol)
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| ChemSpider | |||
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| Properties | |||
| C7H7F6P | |||
| Molar mass | 236.097 g·mol−1 | ||
| Appearance | white solid | ||
| Melting point | 190–215 °C (374–419 °F; 463–488 K) decomposition | ||
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Tracking categories (test):
Tropylium hexafluorophosphate is an organic compound with the formula C7H7PF6. Containing the tropylium cation and the non-coordinating hexafluorophosphate counteranion, tropylium hexafluorophosphate is a rare example of a readily isolable carbocation. It is a white solid.[1]
This compound may be prepared by the reaction of cycloheptatriene with phosphorus trichloride, followed by hexafluorophosphoric acid.[1][2]
See also
[edit]- Triphenylmethyl chloride, also known as trityl chloride.
References
[edit]- ^ a b Kenneth Conrow (1963). "Tropylium Tetrafluoroborate". Org. Synth. 43: 101. doi:10.15227/orgsyn.043.0101.
- ^ Kane, John L.; Danheiser, Rick L. (2001). "Tropylium Tetrafluoroborate". Encyclopedia of Reagents for Organic Synthesis. Encyclopedia of Reagents for Organic Synthesis. doi:10.1002/047084289X.rt429. ISBN 0-471-93623-5.
Category:Hexafluorophosphate Category:Carbocations Category:Non-benzenoid aromatic carbocycles