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Wikipedia:Manual of Style/Chemistry/Chemicals: Difference between revisions

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→‎Uses and/or reactions: If the application stands alone, the application is either significant enough to merit a paragraph to itself, or insignificant enough not to deserve mention.
→‎Infobox: Fixes here: change subheadings for actual headings; rmv strikethrough in one heading - users w/ screenreaders won't register that strikethrough - add. of proper 'see also' link and minor rewrite of 'see also' section
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{{supplement|interprets=Wikipedia:Manual of Style/Chemistry|MOS:CHEM/Chemicals}}
Articles under the Chemicals wikiproject should have the following general layout:
{{MOSCHEM}}
 
=== Infobox ===
The appropriate infobox to use is {{tl|Chembox}}. It is a modular, expandable infobox. Just use the parameters which you need; empty values will not be displayed. Chemboxes should be used for '''all''' chemical compounds, so long as they can exist in that form, even for compounds which are not isolable in pure, solvent-free form (e.g. [[hypochlorous acid]]). Chemboxes should not be used for ions, polymers, and proteins and enzymes (except simple peptides).
 
To include a chembox in an article:
 
#Open {{tl|Chembox}} and copy the relevant (simple, medium, full) box desired, and paste into a [[text editor]]
#Open the relevant reference (e.g. MSDS, Merck Index, CRC Handbook, etc.) and input the data into the template
#Copy the filled-out template into the relevant Wikipedia article.
 
For formatting reasons, the code for the infobox should be '''''{{em|at the very beginning''}}''' of the source code.
 
=== Introductory paragraph ===
:''{{See also: [[|Wikipedia:Lead section]]''}}
Introductory paragraph should classify the compound either generally ([[organic compound]] vs [[inorganic compound]]) or more specifically (e.g., [[organometallic compound]] or [[organoarsenic compound]]). A few properties should be described, assuming [[Standard conditions for temperature and pressure|STP]] and noteworthy features mentioned (e.g. extreme toxicity, odor, hygroscopicity). For simpler organic compounds, the main functional group is mentioned, whereas for complex molecules, a parent molecule should be mentioned. Alternative names and routine properties (m.p., density) are ordinarily placed in the Chembox, not in the lede.
 
Introductory paragraph should classify the compound either generally ([[organic compound]] vs [[inorganic compound]]) or more specifically (e.g., [[organometallic compound]] or [[organoarsenic compound]]). A few properties should be described, assuming [[Standard conditions for temperature and pressure|STP]], and noteworthy features should be mentioned (e.g. extreme toxicity, odor, hygroscopicity). For simpler organic compounds, the main functional group is mentioned, whereas for complex molecules, a parent molecule should be mentioned. Alternative names and routine properties (m.p., density) are ordinarily placed in the Chembox, not in the lead.
===Properties===
This section is often not needed. A discussion of properties is more important for chemicals encountered in everyday life and for solids, where “collective" properties (magnetism, hardness, conductivity) are important. The properties of small organic molecules can be surmised from data in the Chembox and generally do not require extended discussion. Often this section is combined with a description of structure, which summarizes the molecular structure and/or crystal packing (for extended solids). Bond distances are quoted in picometers or [[angstrom]]s.
 
Articles on chemical compounds differ from most other articles in Wikipedia because many names often apply to any given compound. Therefore all but the most prominent names are placed in the "other names" slot on the ChemBox.
=== Occurrence ===
 
==Properties==
This section is often not needed. A discussion of properties is more important for chemicals encountered in everyday life and for solids, where "collective" properties (magnetism, hardness, conductivity) are important. The properties of small organic molecules can be surmised from data in the Chembox and generally do not require extended discussion. Often this section is combined with a description of structure, which summarizes the molecular structure or crystal packing (for extended solids). Bond distances are quoted in picometers or [[angstrom]]s.
 
==Occurrence==
If the compound occurs naturally, it can be mentioned here. If natural sources are industrially significant, some discussion should be included. Avoid one-sentence sections — such data can be left in the lead.
 
===Preparation ===
All articlesArticles about [[chemical compound]]s should include one or more methods of preparation, usually in this order:
*industrial production. Production figures give readers a sense of the commercial significance of a compound.
*biosynthesis
*laboratory-scale preparation
Different methods of synthesis/production may merit full-fledged subheadings. Even articles about compounds that are normally extracted from minerals (''e.g.'' [[molybdenum disulfide]]) should ideally have a laboratory route to the same compound. Mention should be made if a compound is routinely available commercially.
 
*Industrial production. Production figures give readers a sense of the commercial significance of a compound. Typical sources of such information are trade journals such as Chemical and Engineering News and references sources such as Ullmann's Encyclopedia of Industrial Chemistry.
Where appropriate, the first synthesis/first characterization of each compound should be mentioned and referenced to the original article. Apart from that, "foolproof" syntheses such as those listed in [[Organic Syntheses]] and [[Inorganic Syntheses]] are preferred. Patented syntheses should be phrased carefully — e.g. "xxx may be synthesized from ... " Being patented does not mean that this synthesis is the best, or that it is used industrially.
*Biosynthesis
*Laboratory-scale preparation
 
Different methods of synthesis/production may merit full-fledged subheadings. Even articles about compounds that are normally extracted from minerals (e.g. [[molybdenum disulfide]]) should ideally have a laboratory route to the same compound. Mention should be made if a compound is routinely available commercially.
 
Where appropriate, the first synthesis/first characterization of each compound is described with a reference to the original article. Apart from that, "foolproof" syntheses such as those listed in [[Organic Syntheses]] and [[Inorganic Syntheses]] are preferred. Patented syntheses should be phrased carefully — e.g. "xxx may be synthesized from ... " Patents are usually inferior sources owing to their undependable reliability, accessibility, and clarity.
 
When writing about preparations, remember that [[WP:NOT#MANUAL|Wikipedia is not a manual or textbook]]. In general, preparations should be described in general terms, not as step-by-step instructions giving specific amounts, times, conditions, equipment, and details such as methods of stirring and separation.
 
=== Uses and/or reactions ===
The order of presentation and allocation of content should reflect the scale of the individual applications. Large-scale applications should be listed first. Lay editors will naturally tend to enumerate domestic uses. Wikipedia does not aspire to report all niche uses. Avoid lists: try to group the various uses by similarity into a coherent paragraph. If the application stands alone, the application is either significant enough to merit a paragraph to itself, or insignificant enough not to deserve mention.
 
If reactions are to be described, emphasize the well established reactions (e.g. those in [[Organic Syntheses|Organic]] and [[Inorganic Syntheses]]). Highly specialized reactions that are neither broadly applicable nor illustrative are inappropriate.
 
=== History ===
This paragraph, which is optional, should include the discovery/first synthesis of this compound. Past industrial processes can be described as well. If the etymology of the compound is complicated, it can be included here as well, instead of in the lede.
 
==Inclusion of suppliers==
=== Safety ===
Wikipedia is [[WP:NOTCATALOGUE|not a buyer's guide]]. {{em|Do not}} include suppliers' information as they are spam magnets. Such lists are unmaintainable and cause problems. If, however, a particular compound is produced by only one or two suppliers, the suppliers names might be relevant.
The majority of compounds are described by a long list of potential hazards as well as R&S phrases. Even innocuous chemicals such as [[sodium chloride]] have risk and safety phrases: R36, S26, S36 in their [http://msds.chem.ox.ac.uk/SO/sodium_chloride.html MSDSs]. Wikipedia does not aspire to be an MSDS. The hazards associated with a chemical compound should ordinarily be described in the Chembox (via EUClass, NFPA, or MainHazard parameters; further elaborated in R and S phrases). The information in the Chembox is sufficient for most compounds. News reports of routine accidents, even though they may be tragic, are usually not relevant.
 
Three main rules:
*If the hazards are relatively obvious (e.g. [[hexafluorophosphoric acid]] is a strong acid, and should not be stored with bases and reactive metals) do not create a separate sub-section here.
*The description of hazards should avoid speculation. This is partly an extension of Wikipedia [[WP:NPOV|NPOV]] policy, but not entirely. There is no need to include a section which merely states "all chemical compounds should be treated with the utmost precaution": such a section tells the reader nothing. If there are no known (or reasonably suspected) hazards, there is nothing for Wikipedia to say.
*The description of hazards should avoid hyperbole. The role of Wikipedia is to give balanced and accurate information, to allow its readers to reach their own conclusions.
 
Descriptions of hazards should, as far as possible, be based on published, peer-reviewed sources (which should, of course, be cited at the appropriate point in the article). A list of resources for chemical safety information is given in the external links section of these guidelines.
 
==== Toxicology ====
Depends on the extent of the information, this content may be incorporated into the Safety section or it may be a separate. If the compound is a drug, follow [[Wikipedia:WikiProject Drugs]]' recommendations.
 
===<s>Suppliers</s> ===
Wikipedia is not a buyer's guide. ''Do not'' include suppliers' information as they are spam magnets. Such lists are unmaintainable and cause problems. If, however, a particular compound is produced by only one or two suppliers, the suppliers names might be relevant.
 
=== See also ===
Add '''concepts''' in this case. Do not use "See also" to list similar chemical compounds. Use the {{tl|Chembox Related}} module in {{tl|Chembox}} for this purpose.
 
=== References ===
:''See:'' [[Wikipedia:Footnotes]], [[Wikipedia:Cite your sources]]
References should emphasize comprehensive sources, see [[WP:PRIMARY]]. For books, [[ISBN]]’s are helpful. For journal articles, full titles and [[DOI]]’s are desirable.
There is [[Wikipedia_talk:WikiProject_Chemicals#Style_Guide|consensus]] that the <nowiki><ref></nowiki> style of inline citations is to be used throughout articles concerning chemicals. It is preferable to use {{tl|cite journal}}, {{tl|cite encyclopedia}}, and {{tl|cite web}}, though this is not mandatory. For papers published in [[Organic Syntheses]], there is a special citation template ({{tl|OrgSynth}}), which is simpler to fill in.
 
References should come in a numbered list immediately before the ''External links'' section. If footnotes are also used, these should be interspersed with the references and the heading changed accordingly. Notes and references should be numbered sequentially throughout the article by superscript Arabic numerals.
 
There is no consensus in Wikipedia as a whole for the format of the references, although [[APA style]] is suggested as a guideline: this is almost identical to the style used in [[American Chemical Society|ACS]] journals such as ''[[Journal of the American Chemical Society|J. Am. Chem. Soc.]]'' Wikipedia offers a number of citation templates which reproduce this style.
 
Some commonly used textbook have their own citation templates:
 
{| class="wikitable"
|-
! Template
! Reference
|-
| {{t1|BLB}}
| {{BLB}}
|-
| {{tl|Cotton&Wilkinson4th}}
| {{Cotton&Wilkinson4th}}
|-
| {{tl|Cotton&Wilkinson6th}}
| {{Cotton&Wilkinson6th}}
|-
| {{tl|Greenwood&Earnshaw}}
| {{Greenwood&Earnshaw}}
|-
| {{t1|Loudon}}
| {{Loudon}}
|-
| {{tl|March4th}}
| {{March4th}}
|-
| {{tl|McMurray}}
| {{McMurray}}
|-
| {{tl|Merck12th}}
| {{Merck12th}}
|-
| {{tl|RubberBible53rd}}
| {{RubberBible53rd}}
|-
| {{tl|RubberBible83rd}}
| {{RubberBible83rd}}
|-
| {{tl|RubberBible86th}}
| {{RubberBible86th}}
|-
| {{tl|Stryer}}
| {{Stryer}}
|-
| {{tl|VogelOrganic}}
| {{VogelOrganic}}
|-
| {{tl|VogelQualitative}}
| {{VogelQualitative}}
|-
| {{tl|VogelQuantitative}}
| {{VogelQuantitative}}
|}
 
=== External links ===
Avoid adding external links to general sites. Rather, link to the particular article which is relevant. There is absolutely no need to link every national or state regulatory body for a regulated chemical. Instead, use them as inline references in the body of the article, if necessary.
 
A certain number of frequently used sites have their own templates for the external link. Note that some of these templates need parameters to specify a link to a specific page on the website; read the documentation for the individual template for more details.
 
==See also==
{| class="wikitable"
The "See also" section should include '''concepts''' - do not use this section to list similar chemical compounds. Use the {{tl|Chembox Related}} module in {{tl|Chembox}} for this purpose.
|-
! Template
! Link
|-
| {{tl|ecb}}
| {{ecb}}
|-
| {{tl|nist}}
| {{nist}}
|-
| <nowiki>{{</nowiki>[[:Template:ICSC|ICSC]]<nowiki>|xxyy|xx}}</nowiki>
| {{ICSC|xxyy|xx}}
|-
| {{tl|inrs}}
| {{inrs}}
|-
| <nowiki>{{</nowiki>[[:Template:PubChemLink|PubChemLink]]<nowiki>|xxx}}</nowiki>
| {{PubChemLink|xxx}}
|-
| {{tl|SDBS}}
| {{SDBS}}
|-
| {{tl|webelements}}
| {{webelements}}
|-
| {{tl|GoldBookRef}}
| {{GoldBookRef}}
|}
 
[[Category:Wikipedia Manual of Style (chemistry)]]
=== Categories ===
[[Category:Wikipedia essays and information pages about the Manual of Style]]
as necessary
=== Interwiki links ===
as necessary