CN100580064C - Methanol gasoline for vehicle - Google Patents
Methanol gasoline for vehicle Download PDFInfo
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- CN100580064C CN100580064C CN200710045098A CN200710045098A CN100580064C CN 100580064 C CN100580064 C CN 100580064C CN 200710045098 A CN200710045098 A CN 200710045098A CN 200710045098 A CN200710045098 A CN 200710045098A CN 100580064 C CN100580064 C CN 100580064C
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Abstract
The invention discloses an energy-efficient, environment-friendly and high-efficient and low-cost automobile methanol gasoline. The methanol gasoline consists of (calculated by weight percent) gasoline (20-48 percent), methanol (30-70 percent), light hydrocarbon (5-15 percent) and additives (5-7 percent); the additives in the automobile methanol gasoline consists of (calculated by weight percent) solubilizer (1.5-5 percent), anti-oxidant (0.05-0.2 percent), antifreezing agent (0.5-1.0 percent), heat-value increasing agent (0.5-1.0 percent), plasticizer (0.05-0.5 percent), antioxidant (0.05-0.2 percent), stabilizer (0.2-0.8 percent) and antiseptic agent (0.2-1.0 percent). The raw materials required by the automobile methanol gasoline are available from extensive resources and the price is low; suitable for mass production and the production process is very simple; besides, the production is not restricted by seasons or scale.
Description
Technical field
The present invention relates to a kind of Vehicular methanol petrol, belong to the vehicle alcohol group fuel technical field.
Background technology
At present, the production of required indispensable fuel-gasoline during as automobilism is that refinery utilizes oil to obtain through multiple working procedure under complicated technology and corresponding apparatus condition for raw material.Because oxygen level is lower in this kind gasoline, it is insufficient to burn in engine, and the content of lead content, CO and CH is higher in institute's discharge tail gas, has seriously polluted people's living environment.In order to address the above problem, people change explained hereafter and have gone out white gasoline, make moderate progress though use the back environmental pollution, and its production cost rises significantly, and especially the rising of low-alkene gasoline production cost is bigger, applies difficulty.In addition, along with developing of automobile industry, the gasoline demand amount constantly increases, as the but constantly minimizing thereupon of prospective oil of Nonrenewable energy resources, therefore the substitute of large quantities of motor spirit fuel is arisen at the historic moment, with situation that solves undue dependence oil and the environmental issue of more and more paying attention to.What research was maximum in the prior art is alcohol-group fuel, as ethanol petrol and methanol gasoline, because ethanol extracts from grain, though be renewable resources, but the whole world has many countries itself just having contradiction aspect arable land and the grain resource, and ethanol petrol fuel easily produces carbon deposit when using and influence engine work-ing life, so the substitute that has gasoline now with the ethanol petrol conduct is infeasible.In recent years, methanol gasoline has progressively caused everybody concern as vehicle fuel, this is because methyl alcohol has the oxygen level height, characteristics such as volatility is good, the latent heat of vaporization is big, wide material sources, production cost is low, combustion efficacy good, environmental pollution is little, be considered to gasoline substitute preferably, but methanol gasoline particularly research and development, the production of gasoline with high carbinol content can face following technical barrier: 1) corrodibility is strong; 2) calorific value is low; 3) easily produce vapour lock; 4) vaporization heat is big; 5) easily layering.Though disclose multiple solution in the prior art, as Chinese patent CN1332227, CN1364856, CN1371963, CN1381551, CN1410520, CN1429893, CN1487060, CN1508234, CN1521243, CN1563287, CN1580204, CN1712501, CN1727452, CN1743432, CN1754948, CN1821359, CN1821360, CN1827751, CN1876775, CN1884448, CN1884449, CN1891794, CN1923977, CN101012394, CN101012395 and CN101012398, but technique scheme or fail to solve well lamination problem, the additive that adds is too much, thereby make complex process, noxious gas emission increases, burning back knot charcoal increases or the additive source shortage of using or the use that is under an embargo, and is difficult to form and produces in batches; Store instability, burning, discharging difficulty; Strengthened the extent of corrosion of engine fuel system; Need transform automotive engine component; There is the cost height, anti-knocking property are poor, energy-saving effect is poor, exhaust emissions exceeds standard or can not mix a series of problems and defectives such as use with other oil products, therefore, Vehicular methanol petrol fails to be applied always, people need badly solve a kind ofly can manufacture, abrasive, high environmental protection, high-performance and Vehicular methanol petrol cheaply.
Summary of the invention
The objective of the invention is at above-mentioned existing in prior technology problem and defective, provide a kind of and can manufacture and energy-saving and environmental protection, efficiently reach Vehicular methanol petrol with low cost.
For achieving the above object, the present invention is achieved by the following technical programs:
A kind of Vehicular methanol petrol, form by weight ratio by following raw material:
Gasoline 20～48%
Methyl alcohol 30～70%
Lighter hydrocarbons 5～15%
Additive 5～7%
In the gross weight of Vehicular methanol petrol, described weight of additive consists of:
Solubilizing agent 1.5～5%
Non-emulsifying agent 0.5～1.0%
Frostproofer 0.5～1.0%
Improve heat value agent 0.5～1.0%
Softening agent 0.05～0.5%
Antioxidant 0.05～0.2%
Stablizer 0.2～0.8%
Sanitas 0.2～1.0%
Described solubilizing agent is any one or the mixture wherein in sherwood oil, o-Xylol, butanone, pimelinketone, methyl ethyl diketone, ethyl isobutyrate, the diethyl carbonate;
Described non-emulsifying agent is propyl carbinol or sec-butyl alcohol or both mixtures;
Described frostproofer is a Virahol;
Described raising heat value agent is any one or the mixture wherein in enanthol, isopropyl ether, dodecane, pure isooctane, the glycol dibromide;
Described softening agent is the mixture of any one or two kinds in oleic acid and dibutylamine, triacetin, the xylenol;
Described antioxidant is to methoxyl group phenol or xylenol or both mixtures;
Described stablizer is an isobutylamine;
Described sanitas is the mixture of any one or two kinds in dicyclohexyl amine nitrite and Virahol, dibutylamine, the triacetin.
The required supplementary material wide material sources of Vehicular methanol petrol of the present invention, low price, suitable batch production; The oily mutual solubility of alcohol is good, and accumulating is difficult for layering; Have that energy-saving and emission-reduction, powerful, noise are low, high temperature does not have vapour lock, low-temperature cool starting is good, use not premium properties such as carbon deposit; The automobile that is applicable to various spark ignition engines uses, and need not to change motor car engine and bunkering facilities when using, and can mix use arbitrarily with the regular gasoline and the ethanol petrol of the various trades mark; The motor vehicle exhaust clean environment firendly can reach No. 3 standards in Europe, near No. 4 standards in Europe; Vehicular methanol petrol production technique of the present invention is simple, produces not limited by season and scale, and cost is low, can introduce to the market as tank oil, alleviates the contradiction of petroleum products, suppresses rise of the oil price, also helps the development and utilization of the renewable energy resources.
Embodiment
The invention will be further described below by embodiment, and its purpose only is better to understand content of the present invention and unrestricted protection scope of the present invention:
Embodiment 1
The weight of the Vehicular methanol petrol that present embodiment provides consists of:
Gasoline 20%
Methyl alcohol 70%
Lighter hydrocarbons 5%
Additive 5%
In the gross weight of Vehicular methanol petrol, described weight of additive consists of:
Solubilizing agent 1.5%
Non-emulsifying agent 1.0%
Frostproofer 1.0%
Improve heat value agent 0.5%
Softening agent 0.2%
Antioxidant 0.1%
Stablizer 0.3%
Sanitas 0.4%
Wherein: solubilizing agent is made up of any one or mixture wherein in sherwood oil, o-Xylol, butanone, pimelinketone, methyl ethyl diketone, ethyl isobutyrate, the diethyl carbonate; Non-emulsifying agent is made up of any one or its mixture in propyl carbinol, the sec-butyl alcohol; Frostproofer is made up of Virahol; Improving heat value agent is made up of any one or mixture wherein in enanthol, isopropyl ether, dodecane, pure isooctane, the glycol dibromide; Softening agent is made up of the mixture of any one or two kinds in oleic acid and dibutylamine, triacetin, the xylenol; Antioxidant is by any one or its mixture in methoxyl group phenol, the xylenol is formed; Stablizer is made up of isobutylamine; Sanitas is made up of the mixture of any one or two kinds in dicyclohexyl amine nitrite and Virahol, dibutylamine, the triacetin.
The blending process of the Vehicular methanol petrol of present embodiment is as follows:
At first, be mixed in proportion gasoline and lighter hydrocarbons standby; Then, each component with additive is mixed in proportion standby; At last, add methyl alcohol in proportion in methyl alcohol batching storage tank, and under agitation add the mixture of additive and gasoline and lighter hydrocarbons, stirred 1～3 hour, the homogeneous mixture that obtains is methanol gasoline.
With gained oil product sampling Detection, every index all meets the 93# gasoline standard, and wherein octane value and anti-knock index are better than 93# gasoline greatly, and detected result is shown in Table 1 in detail.
Embodiment 2
The weight of the Vehicular methanol petrol that present embodiment provides consists of:
Gasoline 25%
Methyl alcohol 55%
Lighter hydrocarbons 15%
Additive 5%
In the gross weight of Vehicular methanol petrol, described weight of additive consists of:
Solubilizing agent 1.8%
Non-emulsifying agent 0.5%
Frostproofer 0.5%
Improve heat value agent 0.6%
Softening agent 0.15%
Antioxidant 0.05%
Stablizer 0.6%
Sanitas 0.8%
Wherein: solubilizing agent is made up of any one or mixture wherein in sherwood oil, o-Xylol, butanone, pimelinketone, methyl ethyl diketone, ethyl isobutyrate, the diethyl carbonate; Non-emulsifying agent is made up of any one or its mixture in propyl carbinol, the sec-butyl alcohol; Frostproofer is made up of Virahol; Improving heat value agent is made up of any one or mixture wherein in enanthol, isopropyl ether, dodecane, pure isooctane, the glycol dibromide; Softening agent is made up of the mixture of any one or two kinds in oleic acid and dibutylamine, triacetin, the xylenol; Antioxidant is by any one or its mixture in methoxyl group phenol, the xylenol is formed; Stablizer is made up of isobutylamine; Sanitas is made up of the mixture of any one or two kinds in dicyclohexyl amine nitrite and Virahol, dibutylamine, the triacetin.
The blending process of the Vehicular methanol petrol of present embodiment is as follows:
At first, be mixed in proportion gasoline and lighter hydrocarbons standby; Then, each component with additive is mixed in proportion standby; At last, add methyl alcohol in proportion in methyl alcohol batching storage tank, and under agitation add the mixture of additive and gasoline and lighter hydrocarbons, stirred 1～3 hour, the homogeneous mixture that obtains is methanol gasoline.
With gained oil product sampling Detection, every index all meets the 93# gasoline standard, and wherein octane value and anti-knock index are better than 93# gasoline greatly, and detected result is shown in Table 1 in detail.
Embodiment 3
The weight of the Vehicular methanol petrol that present embodiment provides consists of:
Gasoline 35%
Methyl alcohol 50%
Lighter hydrocarbons 10%
Additive 5%
In the gross weight of Vehicular methanol petrol, described weight of additive consists of:
Solubilizing agent 3.0%
Non-emulsifying agent 0.5%
Frostproofer 0.5%
Improve heat value agent 0.5%
Softening agent 0.05%
Antioxidant 0.05%
Stablizer 0.2%
Sanitas 0.2%
Wherein: solubilizing agent is made up of any one or mixture wherein in sherwood oil, o-Xylol, butanone, pimelinketone, methyl ethyl diketone, ethyl isobutyrate, the diethyl carbonate; Non-emulsifying agent is made up of any one or its mixture in propyl carbinol, the sec-butyl alcohol; Frostproofer is made up of Virahol; Improving heat value agent is made up of any one or mixture wherein in enanthol, isopropyl ether, dodecane, pure isooctane, the glycol dibromide; Softening agent is made up of the mixture of any one or two kinds in oleic acid and dibutylamine, triacetin, the xylenol; Antioxidant is by any one or its mixture in methoxyl group phenol, the xylenol is formed; Stablizer is made up of isobutylamine; Sanitas is made up of the mixture of any one or two kinds in dicyclohexyl amine nitrite and Virahol, dibutylamine, the triacetin.
The blending process of the Vehicular methanol petrol of present embodiment is as follows:
At first, be mixed in proportion gasoline and lighter hydrocarbons standby; Then, each component with additive is mixed in proportion standby; At last, add methyl alcohol in proportion in methyl alcohol batching storage tank, and under agitation add the mixture of additive and gasoline and lighter hydrocarbons, stirred 1～3 hour, the homogeneous mixture that obtains is methanol gasoline.
With gained oil product sampling Detection, every index all meets the 93# gasoline standard, and wherein octane value and anti-knock index are better than 93# gasoline greatly, and detected result is shown in Table 1 in detail.
Embodiment 4
The weight of the Vehicular methanol petrol that present embodiment provides consists of:
Gasoline 28%
Methyl alcohol 60%
Lighter hydrocarbons 5%
Additive 7%
In the gross weight of Vehicular methanol petrol, described weight of additive consists of:
Solubilizing agent 1.5%
Non-emulsifying agent 1.0%
Frostproofer 1.0%
Improve heat value agent 1.0%
Softening agent 0.5%
Antioxidant 0.2%
Stablizer 0.8%
Sanitas 1.0%
Wherein: solubilizing agent is made up of any one or mixture wherein in sherwood oil, o-Xylol, butanone, pimelinketone, methyl ethyl diketone, ethyl isobutyrate, the diethyl carbonate; Non-emulsifying agent is made up of any one or its mixture in propyl carbinol, the sec-butyl alcohol; Frostproofer is made up of Virahol; Improving heat value agent is made up of any one or mixture wherein in enanthol, isopropyl ether, dodecane, pure isooctane, the glycol dibromide; Softening agent is made up of the mixture of any one or two kinds in oleic acid and dibutylamine, triacetin, the xylenol; Antioxidant is by any one or its mixture in methoxyl group phenol, the xylenol is formed; Stablizer is made up of isobutylamine; Sanitas is made up of the mixture of any one or two kinds in dicyclohexyl amine nitrite and Virahol, dibutylamine, the triacetin.
The blending process of the Vehicular methanol petrol of present embodiment is as follows:
At first, be mixed in proportion gasoline and lighter hydrocarbons standby; Then, the component that is equipped with additive is mixed in proportion standby; At last, add methyl alcohol in proportion in methyl alcohol batching storage tank, and under agitation add the mixture of additive and gasoline and lighter hydrocarbons, stirred 1～3 hour, the homogeneous mixture that obtains is methanol gasoline.
With gained oil product sampling Detection, every index all meets the 93# gasoline standard, and wherein octane value and anti-knock index are better than 93# gasoline greatly, and detected result is shown in Table 1 in detail.
Embodiment 5
The weight of the Vehicular methanol petrol that present embodiment provides consists of:
Gasoline 43%
Methyl alcohol 40%
Lighter hydrocarbons 10%
Additive 7%
In the gross weight of Vehicular methanol petrol, described weight of additive consists of:
Solubilizing agent 3.3%
Non-emulsifying agent 0.75%
Frostproofer 0.75%
Improve heat value agent 0.75%
Softening agent 0.225%
Antioxidant 0.125%
Stablizer 0.5%
Sanitas 0.6%
Wherein: solubilizing agent is made up of any one or mixture wherein in sherwood oil, o-Xylol, butanone, pimelinketone, methyl ethyl diketone, ethyl isobutyrate, the diethyl carbonate; Non-emulsifying agent is made up of any one or its mixture in propyl carbinol, the sec-butyl alcohol; Frostproofer is made up of Virahol; Improving heat value agent is made up of any one or mixture wherein in enanthol, isopropyl ether, dodecane, pure isooctane, the glycol dibromide; Softening agent is made up of the mixture of any one or two kinds in oleic acid and dibutylamine, triacetin, the xylenol; Antioxidant is by any one or its mixture in methoxyl group phenol, the xylenol is formed; Stablizer is made up of isobutylamine; Sanitas is made up of the mixture of any one or two kinds in dicyclohexyl amine nitrite and Virahol, dibutylamine, the triacetin.
The blending process of the Vehicular methanol petrol of present embodiment is as follows:
At first, be mixed in proportion gasoline and lighter hydrocarbons standby; Then, each component with additive is mixed in proportion standby; At last, add methyl alcohol in proportion in methyl alcohol batching storage tank, and under agitation add the mixture of additive and gasoline and lighter hydrocarbons, stirred 1～3 hour, the homogeneous mixture that obtains is methanol gasoline.
With gained oil product sampling Detection, every index all meets the 93# gasoline standard, and wherein octane value and anti-knock index are better than 93# gasoline greatly, and detected result is shown in Table 1 in detail.
Embodiment 6
The weight of the Vehicular methanol petrol that present embodiment provides consists of:
Gasoline 48%
Methyl alcohol 30%
Lighter hydrocarbons 15%
Additive 7%
In the gross weight of Vehicular methanol petrol, described weight of additive consists of:
Solubilizing agent 5.0%
Non-emulsifying agent 0.5%
Frostproofer 0.5%
Improve heat value agent 0.5%
Softening agent 0.05%
Antioxidant 0.05%
Stablizer 0.2%
Sanitas 0.2%
Wherein: solubilizing agent is made up of any one or mixture wherein in sherwood oil, o-Xylol, butanone, pimelinketone, methyl ethyl diketone, ethyl isobutyrate, the diethyl carbonate; Non-emulsifying agent is made up of any one or its mixture in propyl carbinol, the sec-butyl alcohol; Frostproofer is made up of Virahol; Improving heat value agent is made up of any one or mixture wherein in enanthol, isopropyl ether, dodecane, pure isooctane, the glycol dibromide; Softening agent is made up of the mixture of any one or two kinds in oleic acid and dibutylamine, triacetin, the xylenol; Antioxidant is by any one or its mixture in methoxyl group phenol, the xylenol is formed; Stablizer is made up of isobutylamine; Sanitas is made up of the mixture of any one or two kinds in dicyclohexyl amine nitrite and Virahol, dibutylamine, the triacetin.
The blending process of the Vehicular methanol petrol of present embodiment is as follows:
At first, be mixed in proportion gasoline and lighter hydrocarbons standby; Then, each component with additive is mixed in proportion standby; At last, add methyl alcohol in proportion in methyl alcohol batching storage tank, and under agitation add the mixture of additive and gasoline and lighter hydrocarbons, stirred 1～3 hour, the homogeneous mixture that obtains is methanol gasoline.
With gained oil product sampling Detection, every index all meets the 93# gasoline standard, and wherein octane value and anti-knock index are better than 93# gasoline greatly, and detected result is shown in Table 1 in detail.
Table 1 sample detection result
| Interventions Requested | Pure 93 # gasoline | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 | Detection method |
| Anti-knock index (RON+MON)/2 | ≥88 | ＞92 | ＞92 | ＞92 | ＞92 | ＞92 | ＞92 | GB/T503-1995 |
| Research octane number (RON) (RON) | ≥93 | ＞100 | ＞100 | ＞100 | ＞100 | ＞100 | ＞100 | GB/T5487-1995 |
| Lead content g/L | ≤ 0.004 | ＜0.001 | ＜0.001 | ＜0.001 | ＜0.001 | ＜0.001 | ＜0.001 | GB/T8020-1987 |
| 10% vaporization temperature ℃ | ≤60 | 52.3 | 49.8 | 50.7 | 51.5 | 48.6 | 47.9 | GB/T6536-1997 |
| 50% vaporization temperature ℃ | ≤80 | 64.2 | 61.8 | 62.6 | 62.3 | 60.5 | 59.7 | GB/T6536-1997 |
| 90% vaporization temperature ℃ | ≤180 | 165.6 | 162.2 | 163.1 | 163.7 | 161.5 | 160.9 | GB/T6536-1997 |
| Final boiling point ℃ | ≤205 | 173.2 | 175.7 | 176.5 | 174.6 | 177.8 | 178.1 | GB/T6536-1997 |
| Residual quantity % (V/V) | ≤2 | 1.3 | 1.5 | 1.6 | 1.4 | 1.7 | 1.8 | GB/T6536-1997 |
| Vapour pressure Kpa | ≤88 | 53.00 | 55.00 | 56.00 | 54.00 | 57.00 | 58.00 | GB/T8017-1987 |
| Existent gum mg/100mL | ≤4 | 4 | 3 | 3 | 4 | 2 | 1 | GB/T8019-1987 |
| Inductive phase min | ≥480 | 1310 | 1290 | 1280 | 1300 | 1270 | 1260 | GB/T8018-1987 |
| Sulphur content % (m/n) | ≤0.05 | 0.002 | 0.004 | 0.005 | 0.003 | 0.006 | 0.007 | SH/T0253-1992 |
| Mercaptan: doctor test | By | By | By | By | By | By | By | SH/T0174-1992 |
| The copper corrosion level (50 ℃, 3h) | ≤1 | 1 | 1 | 1 | 1 | 1 | 1 | GB/T5096-1985 |
| Water soluble acid or alkali | Do not have | Do not have | Do not have | Do not have | Do not have | Do not have | Do not have | GB/T259-1988 |
| Mechanical impurity | Do not have | Do not have | Do not have | Do not have | Do not have | Do not have | Do not have | Range estimation |
| Moisture % (m/n) | ≤0.3 | 0.09 | 0.08 | 0.08 | 0.09 | 0.06 | 0.05 | GB/T11133-1989 |
| Benzene content % (V/V) | ≤2.0 | 0.1 | 0.2 | 0.2 | 0.1 | 0.3 | 0.4 | SH/T0663-1998 |
| Aromaticity content % (V/V) | ≤30 | 10.0 | 10.5 | 11.0 | 10.0 | 12.0 | 13.0 | Annotate 1 |
| Olefin(e) centent % (V/V) | ≤25 | 14.5 | 15.0 | 15.6 | 14.5 | 16.0 | 17.0 | Annotate 2 |
| Manganese content g/L | ≤ 0.0018 | 0.0025 | 0.0030 | 0.0032 | 0.0030 | 0.0038 | 0.0046 | SH/T0711-2002 |
| Iron level g/L | ≤0.01 | 0.001 | 0.001 | 0.001 | 0.001 | 0.002 | 0.003 | SH/T0712-2002 |
Annotate 1: get and test by SH/T0713-2002 again after the 100ml sample extracts with 50ml water;
Annotate 2: get and test by GB/T11132-202 again after the 100ml sample extracts with 50ml water.
Claims (7)
1. a Vehicular methanol petrol is characterized in that, is made up of by weight ratio following raw material:
Gasoline 20～48%
Methyl alcohol 30～70%
Lighter hydrocarbons 5～15%
Additive 5～7%;
Wherein the weight of additive consists of:
Solubilizing agent 1.5～5%
Non-emulsifying agent 0.5～1.0%
Frostproofer 0.5～1.0%
Improve heat value agent 0.5～1.0%
Softening agent 0.05～0.5%
Antioxidant 0.05～0.2%
Stablizer 0.2～0.8%
Sanitas 0.2～1.0%;
Described raising heat value agent is any one or the mixture wherein in enanthol, isopropyl ether, dodecane, pure isooctane, the glycol dibromide; Described softening agent is the mixture of any one or two kinds in oleic acid and dibutylamine, triacetin, the xylenol.
2. Vehicular methanol petrol according to claim 1 is characterized in that, described solubilizing agent is any one or the mixture wherein in sherwood oil, o-Xylol, butanone, pimelinketone, methyl ethyl diketone, ethyl isobutyrate, the diethyl carbonate.
3. Vehicular methanol petrol according to claim 1 is characterized in that, described non-emulsifying agent is propyl carbinol or sec-butyl alcohol or both mixtures.
4. Vehicular methanol petrol according to claim 1 is characterized in that, described frostproofer is a Virahol.
5. Vehicular methanol petrol according to claim 1 is characterized in that, described antioxidant is to methoxyl group phenol or xylenol or both mixtures.
6. Vehicular methanol petrol according to claim 1 is characterized in that, described stablizer is an isobutylamine.
7. Vehicular methanol petrol according to claim 1 is characterized in that, described sanitas is the mixture of any one or two kinds in dicyclohexyl amine nitrite and Virahol, dibutylamine, the triacetin.
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| CN200710045098A CN100580064C (en) | 2007-08-21 | 2007-08-21 | Methanol gasoline for vehicle |
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| CN200710045098A CN100580064C (en) | 2007-08-21 | 2007-08-21 | Methanol gasoline for vehicle |
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| CN108906012A (en) * | 2018-07-06 | 2018-11-30 | 云南驰宝节能科技有限公司 | A kind of highly enriched gasoline, diesel oil special-purpose catalyst |
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| CN112708480A (en) * | 2020-12-23 | 2021-04-27 | 重庆山玖能源科技发展有限公司 | Methanol gasoline for vehicle |
-
2007
- 2007-08-21 CN CN200710045098A patent/CN100580064C/en not_active Expired - Fee Related
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