CN103194950B - Novel thermoplastic elastomer composite self-adhesion sport field paving coiled material and manufacture process thereof - Google Patents
Novel thermoplastic elastomer composite self-adhesion sport field paving coiled material and manufacture process thereof Download PDFInfo
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- CN103194950B CN103194950B CN201310154566.5A CN201310154566A CN103194950B CN 103194950 B CN103194950 B CN 103194950B CN 201310154566 A CN201310154566 A CN 201310154566A CN 103194950 B CN103194950 B CN 103194950B
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Abstract
The invention relates to a novel thermoplastic elastomer composite self-adhesion sport field paving coiled material. The coiled material comprises a main body layer made of thermoplastic elastomer, wherein a creep deformation self-adhesion layer is arranged on the bottom surface of the main body layer, and the thermoplastic elastomer is prepared by blending and modifying ethylene propylene diene monomer rubber and polyolefin resin. The manufacture process comprises the steps of: blending the ethylene propylene diene monomer rubber, the polyolefin resin and naphthenic oil in proportion, and carrying out twin-screw extrusion, so as to obtain the thermoplastic elastomer; adding an assistant agent and the naphthenic oil, heating and carrying out high-speed stirring and blending, carrying out compound extrusion by utilizing a pin extruder, then carrying out knurling, overlap edge profiling, microwave foaming, vulcanizing and double-roll gluing, and carrying out crimping to prepare the novel thermoplastic elastomer composite self-adhesion paving coiled material after cooling. According to the novel thermoplastic elastomer composite self-adhesion sport field paving coiled material, the shortage of the prior art can be improved, the performance index of the product is improved, and the manufacture process is simple; the controllable thickness is 4-13mm, and the novel thermoplastic elastomer composite self-adhesion sport field paving coiled material is mainly applied to the fields of athletic tracks in sport fields, basketball courts, tennis courts, badminton courts and the like.
Description
Technical field
The present invention relates to a kind of novel thermoplastic elastomer composite self-adhering athletic ground to mat formation volume Materials And Manufacturing Processes, belong to web-handled field.
technical background
Domestic and international coiled material of mating formation for athletic meeting place and parkland is the matrix material of a kind of compounded rubber or rubber and plastics at present, is mainly used in the ground pavement that there is the public place of requirement of shelter runway, court and kindergarten etc.But, just there is surface cracking in 2 to 3 years, seam come unstuck, play the quality problems such as bulge in the problem that coiled material of mating formation exists weather resistance, tackiness agent does not match used in the market; And construction will wait until basal plane complete drying (moisture content is not more than 10%), planeness is not more than discrepancy in elevation 0.2mm, can have a strong impact on construction speed; In addition, its manufacturing process still adopts rubber item production technique, complex procedures, seriously polluted.The present invention adopts terpolymer EP rubber and polyolefin resin blending and modifying to prepare Novel hot plastics elastomer, compound self-adhesive pavement coiled material of novel thermoplastic elastomer is prepared again as body layer, can the deficiencies in the prior art be improved, improve the performance index of product, and manufacturing process be simple.
Summary of the invention
The object of this invention is to provide a kind of novel thermoplastic elastomer composite self-adhering athletic ground to mat formation volume Materials And Manufacturing Processes.
For realizing above object, mat formation coiled material in novel thermoplastic elastomer composite self-adhering athletic ground of the present invention, comprise the body layer be made up of thermoplastic elastomer, body layer bottom surface is provided with creep self-adhesive glue layer, and wherein thermoplastic elastomer is prepared from by terpolymer EP rubber and polyolefin resin blending and modifying.
Mat formation coiled material in novel thermoplastic elastomer composite self-adhering athletic ground of the present invention, its component and weight part are: terpolymer EP rubber 30-76 part, polyolefin resin 24-70 part, rubber carrier 100-120 part, naphthenic oil 20-30 part, vulcanizing agent 5-8.5 part, whipping agent 3-9 part, magnesium oxide 10-29 part, stopping composition 120-130 part, pigment 8-10 part.Wherein polyolefin resin is chlorinated polyethylene resin or acrylic resin.
Preferred component and weight part are: terpolymer EP rubber 30 parts, chlorinated polyethylene resin 70 parts, rubber carrier 100 parts, naphthenic oil 20-30 part, peroxide vulcanizing agent 6-8.5 part, pneumatogen 3-5 part, magnesium oxide 10-15 part, silicon calcium powder 120 parts, iron oxide pigment 8-10 part.
Preferred component and weight part are: terpolymer EP rubber 76 parts, acrylic resin 24 parts, rubber carrier 120 parts, naphthenic oil 20-30 part, sulphur 5-8 part, PC whipping agent 7-9 part, magnesium oxide 15-29 part, fine particle calcium carbonate 130 parts, iron oxide pigment 8-10 part.
Novel thermoplastic elastomer composite self-adhering athletic ground of the present invention coil thickness of mating formation is 4mm-13mm, according to place need can be used for the places such as runway, basketball court, tennis court, court.
Present invention also offers a kind of novel thermoplastic elastomer composite self-adhering athletic ground to mat formation the manufacturing process of coiled material, concrete steps are: terpolymer EP rubber, polyolefin resin, naphthenic oil carry out blended by (1) in proportion, by twin-screw extrusion, extrusion temperature is 210 DEG C, obtains thermoplastic elastomer; (2) in above-mentioned thermoplastic elastomer, rubber carrier, vulcanizing agent, whipping agent, magnesium oxide, stopping composition, pigment and naphthenic oil is added, high-speed stirring, at 215 DEG C, carry out heating blended, by pin forcing machine compound extruded, then carry out embossing and landing edge die mould; (3) through microwave foaming, sulfuration, pair roller gluing, gluing temperature is 140 DEG C, and cooling is curling afterwards makes compound self-adhesive pavement coiled material of novel thermoplastic elastomer.
The beneficial effect that the present invention produces is: terpolymer EP rubber saturation ratio is higher, have excellent aging resistance, but the autohension of terpolymer EP rubber is poor.The present invention is by terpolymer EP rubber and chlorinated polyethylene resin or acrylic resin blending and modifying, obtain novel thermoplastic elastomer, as compound self-adhesive pavement coiled material of novel thermoplastic elastomer prepared by body layer, both the fine quality of terpolymer EP rubber of knowing clearly had been retained, in turn enhance the tensile strength of product, wear resistance and weldability energy, thus improve the physical performance index of product, reduce production cost.In addition, the mat formation preparation technology of coiled material of novel thermoplastic elastomer composite self-adhering athletic ground of the present invention is simple, and contaminative is little.
Embodiment
Embodiment 1:
Mat formation coiled material in a kind of novel thermoplastic elastomer composite self-adhering athletic ground, its component and weight part are: terpolymer EP rubber 30 parts, chlorinated polyethylene resin 70 parts, rubber carrier 100 parts, naphthenic oil 20 parts, peroxide vulcanizing agent 6-8.5 part, pneumatogen 3-5 part, magnesium oxide 10-15 part, silicon calcium powder 120 parts, iron oxide pigment 8 parts.
Mat formation the manufacturing process of coiled material in a kind of novel thermoplastic elastomer composite self-adhering athletic ground, concrete steps are: terpolymer EP rubber, chlorinated polyethylene resin, naphthenic oil carry out blended by (1) in proportion, by twin-screw extrusion, extrusion temperature is 210 DEG C, obtains thermoplastic elastomer; (2) in above-mentioned thermoplastic elastomer, rubber carrier, naphthenic oil, peroxide vulcanizing agent, pneumatogen, magnesium oxide, silicon calcium powder, iron oxide pigment and naphthenic oil is added, high-speed stirring, heating is carried out blended at 215 DEG C, by pin forcing machine compound extruded, then carry out embossing and landing edge die mould; (3) through microwave foaming, sulfuration, pair roller gluing, gluing temperature is 140 DEG C, and after cooling, mat formation coiled material in curling novel thermoplastic elastomer composite self-adhering athletic ground of making.
Embodiment 2:
Mat formation coiled material in a kind of novel thermoplastic elastomer composite self-adhering athletic ground, its component and weight part are: terpolymer EP rubber 76 parts, acrylic resin 24 parts, rubber carrier 120 parts, naphthenic oil 30 parts, sulphur 5-8 part, PC whipping agent 7-9 part, magnesium oxide 15-29 part, fine particle calcium carbonate 130 parts, iron oxide pigment 10 parts.
Mat formation the manufacturing process of coiled material in a kind of novel thermoplastic elastomer composite self-adhering athletic ground, concrete steps are: terpolymer EP rubber, acrylic resin, naphthenic oil carry out blended by (1) in proportion, by twin-screw extrusion, extrusion temperature is 210 DEG C, obtains thermoplastic elastomer; (2) in above-mentioned thermoplastic elastomer, rubber carrier, naphthenic oil, sulphur, PC whipping agent, magnesium oxide, fine particle calcium carbonate, iron oxide pigment and naphthenic oil is added, high-speed stirring, at 215 DEG C, carry out heating blended, by pin forcing machine compound extruded, then carry out embossing and landing edge die mould; (3) through microwave foaming, sulfuration, pair roller gluing, gluing temperature is 140 DEG C, and after cooling, mat formation coiled material in curling novel thermoplastic elastomer composite self-adhering athletic ground of making.
Claims (9)
1. mat formation coiled material in a novel thermoplastic elastomer composite self-adhering athletic ground, comprise the body layer be made up of thermoplastic elastomer, body layer bottom surface is provided with creep self-adhesive glue layer, it is characterized in that: described thermoplastic elastomer is prepared from by terpolymer EP rubber and polyolefin resin blending and modifying; Described novel thermoplastic elastomer composite self-adhering athletic ground coiled material of mating formation is made up of the component of following weight part: terpolymer EP rubber 30-76 part, polyolefin resin 24-70 part, rubber carrier 100-120 part, naphthenic oil 20-30 part, vulcanizing agent 5-8.5 part, whipping agent 3-9 part, magnesium oxide 10-29 part, stopping composition 120-130 part and pigment 8-10 part.
2. mat formation coiled material in a kind of novel thermoplastic elastomer composite self-adhering athletic ground as claimed in claim 1, it is characterized in that: described polyolefin resin is chlorinated polyethylene resin or acrylic resin.
3. mating formation coiled material in a kind of novel thermoplastic elastomer composite self-adhering athletic ground as described in claim 1, it is characterized in that: it is made up of the component of following weight part: terpolymer EP rubber 30 parts, chlorinated polyethylene resin 70 parts, rubber carrier 100 parts, naphthenic oil 20-30 part, peroxide vulcanizing agent 6-8.5 part, pneumatogen 3-5 part, magnesium oxide 10-15 part, silicon calcium powder 120 parts and iron oxide pigment 8-10 part.
4. mating formation coiled material in a kind of novel thermoplastic elastomer composite self-adhering athletic ground as described in claim 1, it is characterized in that: it is made up of the component of following weight part: terpolymer EP rubber 76 parts, acrylic resin 24 parts, rubber carrier 120 parts, naphthenic oil 20-30 part, sulphur 5-8 part, PC whipping agent 7-9 part, magnesium oxide 15-29 part, fine particle calcium carbonate 130 parts and iron oxide pigment 8-10 part.
5. mating formation coiled material in a kind of novel thermoplastic elastomer composite self-adhering athletic ground as described in claim 1, it is characterized in that: described coil thickness is 4mm-13mm, be applicable to runway, basketball court, tennis court, court.
6. mat formation a manufacturing process for coiled material in novel thermoplastic elastomer composite self-adhering athletic ground, it is characterized in that: terpolymer EP rubber, polyolefin resin, naphthenic oil carry out blended by (1) in proportion, by twin-screw extrusion, obtain thermoplastic elastomer; (2) in above-mentioned thermoplastic elastomer, add rubber carrier, vulcanizing agent, whipping agent, magnesium oxide, stopping composition, pigment and naphthenic oil, it is blended to carry out heating high-speed stirring, by pin forcing machine compound extruded, then carries out embossing and landing edge die mould; (3) through microwave foaming, sulfuration, pair roller gluing, cooling is curling afterwards makes compound self-adhesive pavement coiled material of novel thermoplastic elastomer.
7. mat formation the manufacturing process of coiled material in a kind of novel thermoplastic elastomer composite self-adhering athletic ground as claimed in claim 6, it is characterized in that: in described step (1), twin-screw extrusion temperature is 210 DEG C.
8. mating formation the manufacturing process of coiled material in a kind of novel thermoplastic elastomer composite self-adhering athletic ground as described in claim 6, it is characterized in that: in described step (2), Heating temperature is 215 DEG C.
9. mating formation the manufacturing process of coiled material in a kind of novel thermoplastic elastomer composite self-adhering athletic ground as described in claim 6, it is characterized in that: in described step (3), gluing is creep self-adhesive, and gluing temperature is 140 DEG C.
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| CN201310154566.5A CN103194950B (en) | 2013-04-28 | 2013-04-28 | Novel thermoplastic elastomer composite self-adhesion sport field paving coiled material and manufacture process thereof |
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| CN201310154566.5A CN103194950B (en) | 2013-04-28 | 2013-04-28 | Novel thermoplastic elastomer composite self-adhesion sport field paving coiled material and manufacture process thereof |
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| CN103194950B true CN103194950B (en) | 2015-03-25 |
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Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106832492A (en) * | 2015-12-04 | 2017-06-13 | 宜兴市森泰塑胶有限公司 | Environment friendly plastic rubber material |
| KR102257975B1 (en) * | 2015-12-22 | 2021-05-27 | 노라 시스템즈 게엠베하 | Adhesive-equipped floor covering and manufacturing method thereof |
| CN105694248A (en) * | 2016-03-18 | 2016-06-22 | 淄博世纪联合新型建筑材料有限公司 | TPE (thermal plastic elastomer) and application thereof |
| CN106700287B (en) * | 2016-12-19 | 2019-03-01 | 宁波泰甬汽车零部件有限公司 | A kind of foamed thermoplastic elastomers and preparation method thereof |
| CN108867244A (en) * | 2017-05-10 | 2018-11-23 | 巴斯夫欧洲公司 | By the terrace of the composite material preparation comprising foamed thermoplastic elastomers particle |
| CN108440822B (en) * | 2018-03-16 | 2021-05-04 | 南京工程学院 | Thermoplastic foaming particle filled plastic track and preparation method thereof |
| CN108906551A (en) * | 2018-06-28 | 2018-11-30 | 常州市顺祥新材料科技有限公司 | A kind of preparation method and applications of thermoplastic expanded particle coiled material |
| CN109438859A (en) * | 2018-10-15 | 2019-03-08 | 道高分子聚合物（宁波）有限公司 | A kind of plastic cement race track thermoplastic elastomer (TPE) and preparation method thereof |
| CN109486033A (en) * | 2018-10-15 | 2019-03-19 | 道高分子聚合物（宁波）有限公司 | Plastic cement race track thermoplastic elastomer (TPE) and preparation method thereof |
| CN111925602A (en) * | 2020-07-21 | 2020-11-13 | 苏州大乘环保新材有限公司 | MPV modified runway particle and preparation method thereof |
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| CN1304476C (en) * | 2005-04-21 | 2007-03-14 | 上海交通大学 | Method for preparing tribasic ethylene propylene rubber/polypropylene thermoplastic elastomer |
| CN1900207B (en) * | 2006-07-04 | 2012-05-02 | 珠海华兴防水科技有限公司 | Self adhesive and high molecule self adhesive water-proof coil and producing process |
| CN201214860Y (en) * | 2008-05-06 | 2009-04-01 | 秦雪辰 | High-molecular self-adhering water-proof rolled material |
| CN101497721B (en) * | 2009-02-26 | 2011-08-24 | 江苏工业学院 | Foam material and moulding method thereof |
| CN101824189B (en) * | 2010-04-21 | 2011-11-23 | 北京市射线应用研究中心 | Preparation process of ethylene propylene diene rubber foaming materials |
| CN201746764U (en) * | 2010-08-31 | 2011-02-16 | 陈行忠 | Compound self-adhesive pavement coiled material of novel thermoplastic elastomer |
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Effective date of registration: 20161019 Address after: 528000 Guangdong province Foshan city Shunde District Ronggui Huangpu small neighborhood in Guangxi Road No. 66 of two layers Patentee after: Guangdong Gaojie Sports Industry Co.,Ltd. Address before: 528312 No. 66 North Guangxi Road, Ronggui hi tech Zone, Shunde District, Guangdong, Foshan Patentee before: Chen Xingzhong Patentee before: Qin Xuechen |
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Address after: 528000 One of the Second Floor of No. 66 Chaoguibei Road, Xiaohuangpu Residential Committee, Ronggui, Shunde District, Foshan City, Guangdong Province Patentee after: Gaojie Sports Co.,Ltd. Address before: 528000, Floor 1, No. 66, Chaogui North Road, Ronggui Xiaohuangpu Neighborhood Committee, Shunde District, Foshan City, Guangdong Province Patentee before: Guangdong Gaojie Sports Industry Co.,Ltd. |