CN103342032B

CN103342032B - Laminated identification document

Info

Publication number: CN103342032B
Application number: CN201310142172.8A
Authority: CN
Inventors: 约瑟夫·费尔德曼; 阿纳托利·利普金; 马克·M·珀辛科
Original assignee: Individual
Current assignee: Individual
Priority date: 2006-11-06
Filing date: 2007-11-05
Publication date: 2016-01-06
Anticipated expiration: 2027-11-05
Also published as: CN101573242B; US20130009347A1; US20080106002A1; CA2668820A1; BRPI0718653A2; KR101489008B1; CN103342032A; US8551387B2; US8304061B2; CA2668820C; CN101573242A; KR20090088393A; EP2084014A2; EP2084014B1; WO2008057495A3; HK1133234A1; EP2084014A4; WO2008057495A9; AU2007317875B2; WO2008057495A2

Abstract

A kind of have multiple laminate layers and it have the laminated identification document of recognition image.Described certificate comprises: the core laminate with upper surface and lower surface, be printed with lattice diagram on the surface at least one of described core laminate, and at least one vision is nontransparent or reflective laminate layer is attached to described printed surface and cover described printed surface.Once make the multiple part of described laminate layers produce trace point, the described lattice diagram be printed on described core laminate is appeared, to form described recognition image thus.The laminated identification document of laser index carving can comprise multiple laminate layers, wherein compatibility layer is attached to multiple adjacent laminate layers, and described compatibility layer comprises can by the image forming material of laser index carving.Have multiple laminate layers and it have the laminated identification document of recognition image, wherein at least one laminate layers is compatibility layer.

Description

Laminated identification document

The application is the divisional application that the application number submitted on November 5th, 2007 is 200780049316.8, denomination of invention is the application for a patent for invention of " laminated identification document ".

related application: this application claims that submit, that sequence number is the U.S. Provisional Application of 60/857,031 priority on November 6th, 2006.

Technical field

The present invention relates to the lamination type certificate requiring safety.More specifically, the present invention relates to laminated identification document (identificationdocument), passport and smart card, and the security doc-uments of other similar type.

Background technology

The checking of individual's true identity is a problem increasingly increased.Identity theft is rampant, and the identity of stealing has been used to implement the attack of terrorism.Stolen key, password and the code in computer network and safety zone is broken through.

Conventional scheme is typically included in identification certificate certificate with biomarker, and the photograph image of described biomarker such as authorized holder or fingerprint, described biomarker is protected to exempt from by one or more security feature and distorted.

Another kind of scheme is the scheme being called smart card or the intelligent pass.Typical smart card comprises core (core) layer, and described core layer is preferably preprinted and is brushed with such as personal information.Typically, in this preprinted inserting or complete before installation smart card module core.If necessary, high-quality image and text can all be printed in the both sides of core.Then, preferably cover the core of printing with laminate layers, the core of described laminate layers protection preprinted is not invaded, and the wearing and tearing occurred when protecting it to prevent every day from using and tearing.Subsequently, in laminate structures, form cavity, and integrated circuit modules is fixed in the cavity.The antenna being connected to intelligent card chip is embedded in card sometimes, to allow to be communicated by radio frequency.

Authorize the U.S. Patent No. 6 of Jones etc., 843,422 practices broadly describing current manufacture contactless and contact intelligence certificate, described intelligent certificate is used for postponing distribution and distribution from concentrated position and at once issuing from position (over-the-counterlocation) outside the venue and distribute.Also be used in middle practices described such as Jones and manufacture other lamination types mark carrying goods.The whole disclosure of Jones etc. is incorporated herein by reference.

For the reason of security, from concentrated position distribution with from the identification card (identificationcard) of nonconcentrated position outside the venue distribution, there is identical functional and outward appearance.The manufacture meeting the card of ISO specification comprises a lot of manufacturing step.Therefore, card is generally also personalized in the time afterwards at non-concentrated position subsequently in concentrated position manufacture.The individualized of printing has generally been come by dye diffusion thermal transfer imaging (D2T2) or laser engraving.The card of D2T2 printing is not for general enough durable long-life ID card (identitycard), and laser engraving card is generally a colored printing in comparative background.Therefore, the personalized image can printing polychrome on the final card meeting ISO specification desired physical considerations is expected.

Jones etc. also describe printing and lamination identification certificate, are based on micropore synthetic paper at the described identification certificate center heart.Such identification certificate can also be the smart card comprising integrated circuit (such as semiconductor chip and interface).Described card can also pass through laser, hot transfer printing and/or offset printing method with identification tag or other image printings, and can comprise such as photograph image, and/or customization or personalized word and data.Poromerics is easier to printing and lamination, because such as can partly flow in the micropore of described material for the ink of lamination and polymeric layer.Ink and laminate layers are attached to core texture by this help, thus realize the certificate more safer than the certificate realized with polymer core.But, micropore core material, such as synthetic paper, has the physics shortcoming some structures being weaker than solid core material, and is comparatively easy to delamination under heat as thermoplastic.Therefore, use solid core by expecting but still while the laminar structure that maintenance is strong, there is good printing capability.

Basic blocking fabrication technique also international card manufacture association (ICMA) website ( www.icma.org), basis is made in Section5-TheBasicsofCardManufacturing(chapter 5-blocking) on disclose.This whole document is incorporated herein by reference.

Standard method of test for identification card is described in ISO/IEC10373-2003 " identification card method of testing and ANSIINCITS322-2002 card durability test method ".The whole disclosure of these documents is incorporated herein by reference.

Jones etc. enumerate other the not enough and problems be associated with normal procedure intelligent card.When contact intelligent card, some in these problems comprise smart card module being bent, ejecting card under the bending stress of infringement smart card module, and/or card itself is worn and torn normally and tearing causes cracking.

The various lamination treatment to identification card in U.S. Patent No. 5,783,024,6,007,660,6,066,594,6,159,327,6,283,188 and 6,003, open in 581.The whole disclosure of these patents is incorporated herein by reference.

Jones etc. represent that most preferred laminate layers is Merlon.Merlon is dystectic rigid polymer, and it can compensate flexible but Merlon is expensive, can not be embossed, unless and coating, otherwise very responsive for scribing impulse fault.This means that if surface is drawn, then it can ftracture by this cut.Jones etc. quote the United States Patent (USP) 6,066,594 of authorizing Gunn and authorize 5,334,573 of Schild and describe acceptor coating this Merlon coated for dye diffusion thermal transfer (D2T2).Jones etc. do not instruct or advise that these acceptor coating are impact modified layers, to reduce the scribing sensitiveness of Merlon.The shortcoming of Gunn and Schild coating is, they are the coating based on solvent, comprises rodent organic solvent, and extraly, and they are for being not desirably environment and work safety problem.These are the solvents that may cause crackle becoming known for Merlon and PET based on some solvents in the coating of solvent, and described crackle causes the cracking in polymer film to be shaped, for example, see EvaluatingEnvironmentalStressCrackingofMedicalPlastics (MPBarchive, May98) (the evolution ESC of medical plastic, MPB archives, in May, 98).Therefore, generally undesirably dicyandiamide solution is used in these types of applications.Extruding of Gunn and Schild coating is possible, but described material require is thermoplastic, and such material can be removed by hot means because it keeps thermoplasticity, namely distorts.

As the primary attractive forces of transparent upper laminate layers, Merlon is that it can marking rank can obtain from the supplier of such as Bayer Bitterfeld GmbH at laser.This allows the permanent marking that burns to be carved in the polymer that will mark by burning.Such burning marking makes the change of data be difficult to or can not realize.The scribing sensitiveness of the unresolved Merlon of such scheme and possibility of cracks, also during unresolved use dye diffusion thermal transfer D2T2 to the personalized needs of colored OTC.Pure Merlon does not accept standard D2T2 printing.

Jones etc. also describe and use various adhesive phase AD1-3, but do not distinguish between thermoplasticity and thermosets.A kind of cohesive material (layer 11 of such as Jones etc. and 13, Fig. 1) can comprise such as KRTY(Transilwrap, FranklinPark, IL).KRTY is polylefin thermoplatic adhesive.What also quote is thermoplastic polyurethane (such as from the CLA93A of ThermedicsInc.).

The United States Patent (USP) 6,905,742 authorizing Konerpalle solves card lamination and marks intimate deal with ID.Konerpalle describes and uses thermoplastic bonded compatibility material, such as ELVAX3175 ethylene vinyl acetate polymer, the ethylene vinyl acetate polymer sour/acrylate modified with BYNEL3101, ELVALOY741 modifier and FUSABOND polymer coupler (E. I. Du Pont de Nemours and Co, Wilmington, DE) porous ink acceptor synthesis layer (such as porous Teslin) extruding layer is pressed onto on more rigid polypropylene core composition.The laminar structure of Konerpalle is based on thermoplastic material and together with thermoplastic material binds, not mentioned thermosets.

All aforementioned reference describe by using the thermoplastic that is attached to each other and/or using thermoplastic adhesives with the means of heat by structural laminated and the security doc-uments that combines and produce.Such material tends to have the fusing point at 80 ° of-170 ° of C.Such thermoplastic polymer can by application warm and cooling subsequently and easily and repeatedly softening and sclerosis.Manufacture lamination aspect from such material and face hot delamination.Such characteristic makes the security doc-uments height made from such material be subject to security to break through and distort.

Jones etc. and Konerpalle pay close attention to such necessity respectively, that is, make porous print surface not only accept typographic(al) mark but also guarantee to comprise the suitable lamination of porous ramie cotton fabric as the structure of RF antenna/chip carrier.

Therefore, relate to hot delamination neurological susceptibility current and weaken in the structure of physical arrangement by using the technique based on solvent, there is serious deficiency.

Laser engraving or marking have improved this year.The U.S. Patent No. 6,342,335 of authorizing Fujita discusses in the progress using laser beam to realize in the image recording laser technological system of high-speed record or high density high image quality record.Image formation system uses the laser thermal recording medium or laser thermal transfer recording materials that are used for register system, and wherein laser beam is converted into heat.The whole disclosure of Fujita etc. is incorporated herein by reference.

Also there is the technology for writing CD or DVD, described technology has different reflexive trace point by generation and realizes marking.Authorize the United States Patent (USP) 7 of Yamamoto, 215,625 describe optical disc recording apparatus, and described device changes reflectivity thus by using laser to form the trace point larger than the point being generally used for digital record and allows visual image to be recorded at light disc recording visual image.Do not exist and use laser engraving trace point in the visible area formation black and white of spectrum or coloured image or any instruction or suggestion being applied to security doc-uments.

Summary of the invention

Target of the present invention is, uses so compatible image forming material, and described material also can still be had very high bonding strength by laser index carving under low power density (being less than 1 watt/micron).Therefore, by reducing explosive laser power and increasing the bonding strength of compatibility structure, people can create can the firm card of laser index carving and CD structure, and it is can not at the delamination of undesirable region or deposition materials again.

Another target of the present invention is, provides one or more compatibilized layer between the laminate layers in identification card structure, and wherein such compatibilized layer can be partially or completely heat cured.

Another target of the present invention is, provides one or more compatibilized layer between the laminate layers in identification card structure, and wherein said identification card structure comprises material that is water base and/or radiation-hardenable, and described material is environmentally acceptable.

Another target of the present invention is, some problem relevant to these card structures is made up by using such a or multiple compatibilized layer in identification card structure, especially, minimize or prevent the bending stress damaging card, and/or prevent card itself from ftractureing due to wearing and tearing normally and tearing.

Another target of the present invention is, smart card module ejecting card when bending is prevented by using this one or more compatibilized layer of conventional die adhesive in replacement smart card, minimize or prevent the bending stress damaging card, and/or prevent card itself from ftractureing due to wearing and tearing normally and tearing.

The present invention again another target is, overcome and the problem using the dicyandiamide solution with aggressivity organic solvent to be associated by using such a or multiple compatibilized layer, described Aggressive solvents causes crackle and causes the craze and transfiguration in polymer film, and for being not desirably environment and work safety problem.

Another target more of the present invention is, such identification card is obtained by using such a or multiple compatibilized layer, described identification card has the transparency at the visible area of 400-800 nanometer and has absorbability to optical maser wavelength, allowing to mark (such as bar code, photo and other comprise the mark of biology or data) be marked with transparent overlay or lamination type white or clean (clear) core.

Another target more of the present invention is, such identification card is obtained by using such a or multiple compatibilized layer, described identification card has the transparency or non-transparency or reflectivity at the visible area of 400-800 nanometer and has absorbability to optical maser wavelength, with allow with multi-color marking (such as bar code, photo and other comprise the mark of biology or data) be marked with nontransparent or reflective coating or lamination type white or clean core.Preferably, recording medium is metallic layers (metalliclayer), and described metallic layers does not interfere RF data to the transmission of non-contact card antenna.

Another target more of the present invention is, such identification card is obtained by using such a or multiple compatibilized layer, described identification card has highly reflective at the visible area of 400-800 nanometer and has absorbability to optical maser wavelength, with allow with multi-color marking (such as bar code, photo and other comprise the mark of biological characteristic or data) be marked with nontransparent or reflective coating or lamination type white or clean core.Preferably, recording medium is nontransparent or the nontransparent layer of part, described layer can become transparent by being exposed to laser energy, such as: cause foam collapse to become solid projection layer when heated---the froth bed of crystal or semi-crystal or liquid crystal layer light scattering layer, once be exposed to laser or other radiation, described froth bed becomes transparent.

Another target more of the present invention is, such identification card is obtained by using such a or multiple compatibilized layer, described identification card has highly reflective at the visible area of 400-800 nanometer and has absorbability to optical maser wavelength, with allow with multi-color marking (such as bar code, photo and other comprise the mark of biology or data) be marked with nontransparent or reflective coating or lamination type white or clean core.Preferably, recording medium is holographic metallic layer, and imaging operation causes discontinuous in this metallic layers, and does not interfere RF data to the transmission of non-contact card antenna.Holographic material can have track to help guide and be similar to the LD Writing/Reading controlling mechanism that CD or DVD writes material.

All preceding aim are all realized by method and structure of the present invention.

In one embodiment, a kind of method for recognition image recording scheduled on the laminated identification document with multiple laminate layers is provided.Described method comprises provides laminated identification document, and described laminated identification document comprises the core laminate with upper surface and lower surface, is printed with lattice diagram on the surface at least one of described core laminate.In addition, at least one visually nontransparent or reflective laminate layer be attached to described printed surface and cover described printed surface.Subsequently, make described nontransparent or reflective laminate layer generation trace point, to enable the part of the described dot matrix be printed on described core laminate be appeared (exposed), form described recognition image thus.

The present invention also provides a kind of method for recognition image recording scheduled on the laminated identification document with multiple laminate layers, described method comprises: a) provide laminated identification document, described laminated identification document comprises: i. has the core laminate of upper surface and lower surface, is printed with lattice diagram on the surface at least one of described core laminate; And ii. is attached to described printed surface and at least one the visually nontransparent or reflective laminate layer covering described printed surface; B) make described nontransparent or reflective laminate layer generation trace point, to enable multiple parts of the described dot matrix be printed on described core laminate be appeared, form described recognition image thus.

In preferred embodiments, the step forming described recognition image comprises: a) provide optical pickup apparatus, for watching the image of described predetermined recognition image; B) provide image encoder, described image encoder generates the data corresponding with described recognition image; C) LD control unit is provided; D) the described data corresponding with described recognition image are transferred to described LD control unit from described image encoder; E) make described nontransparent or reflective laminate layer generation trace point with described LD control unit, to enable multiple parts of the described dot matrix be printed on described core laminate be appeared, form described recognition image thus.

In preferred embodiments, described laminated identification document also comprises the compatibility layer that at least one is attached to multiple adjoining laminate layers, described compatibility layer comprises image forming material, described image forming material can be less than the power density of about 1 watt/micron by laser index carving, and keep being combined with the stickiness of described multiple adjacent layer, can the identification card of laser index carving to be formed thus.

In preferred embodiments, described compatibility layer comprises polymer, and described polymer is selected from by being the group that partially or completely heat cured water based curable polymers or radiation-curable polymer or its mixture form.

In preferred embodiments, described compatibility layer has highly reflective at the visible area of 400-800 nanometer, and has absorbability to optical maser wavelength.

In preferred embodiments, described compatibility layer has the transparency at the visible area of about 400-800 nanometer, and has absorbability to optical maser wavelength.

In preferred embodiments, described compatibility layer can be nontransparent or the nontransparent recording medium of part.

In another embodiment of the invention, provide a kind of can the laminated identification document of laser index carving, described laminated identification document has multiple laminate layers.Described identification certificate comprises the compatibility layer being attached to adjoining laminate layers, described compatibility layer comprises image forming material, described image forming material can be less than the power density of about 1 watt/micron by laser index carving, and keeps being combined with the stickiness of described adjacent layer, can the identification card of laser index carving to be formed thus.

The present invention also provide a kind of can the laminated identification document of laser index carving, described laminated identification document has multiple laminate layers, described identification certificate comprises the compatibility layer being attached to multiple adjoining laminate layers, described compatibility layer comprises image forming material, described image forming material can be less than the power density of about 1 watt/micron by laser index carving, and keep being combined with the stickiness of described multiple adjacent layer, can the identification card of laser index carving to be formed thus.

In another embodiment of the invention, provide and a kind ofly there is multiple laminate layers and it has the laminated identification document of recognition image.Described certificate comprises: the core laminate with upper surface and lower surface, is printed with lattice diagram on the surface at least one of described core laminate.In addition, provide and be attached to described printed surface and cover the nontransparent or reflective laminate layer of at least one vision on described printed surface.Once make described laminate layers produce trace point, the part being printed on the described lattice diagram on described core laminate is appeared, to form described recognition image thus.

The present invention also provides a kind of to be had multiple laminate layers and it has the laminated identification document of recognition image, described laminated identification document comprises: a. has the core laminate of upper surface and lower surface, is printed with lattice diagram on the surface at least one of described core laminate; And b. is attached to described printed surface and covers the nontransparent or reflective laminate layer of at least one vision on described printed surface; Wherein, once make described laminate layers produce trace point, the multiple parts being printed on the described lattice diagram on described core laminate are appeared, to form described recognition image thus.

In preferred embodiments, described laminated identification document also comprises the compatibility layer that at least one is attached to multiple adjoining laminate layers, described compatibility layer comprises image forming material, described image forming material can be less than the power density of about 1 watt/micron by laser index carving, and keep being combined with the stickiness of multiple described adjacent layer, can the identification card of laser index carving to be formed thus.

In preferred embodiments, described lattice diagram comprises the point of multiple different colours.

In preferred embodiments, described lattice diagram is printed as full frame point.

In preferred embodiments, described nontransparent or reflective laminate layer comprises printing another identification marking thereon.

In preferred embodiments, described identification certificate is also included in the nontransparent or compatibilized layer between reflective laminate layer and described core laminate of described vision, to be bonded to each other by these laminate layers thus.

In yet another embodiment of the present invention, provide and a kind ofly have multiple laminate layers and it have the laminated identification document of recognition image, wherein at least one laminate layers is compatibility layer.

In preferred embodiments, described compatibility layer bleach after being exposed to laser energy.

In preferred embodiments, described compatibility layer is foam, and when being exposed to laser energy, described foam collapse is solid transmissive layer, transparent crystal, semi-crystal or liquid crystal layer.

In preferred embodiments, compatibilized layer is the intermediate layer between core layer and holographic metallic recording layer, and wherein RF data are transmitted by described compatibilized layer.

The present invention also provides a kind of laminated identification document, described laminated identification document comprises: a) compatibilized core laminate, described compatibilized core laminate has upper surface and lower surface, and at least one of described compatibilized core laminate is printed with lattice diagram on the surface; And b) be attached to described printed surface and cover the nontransparent or reflective laminate layer of at least one vision on described printed surface; C) for producing the device of recognition image in described nontransparent or reflective laminate layer, described device makes the part of the described lattice diagram be printed on described core laminate be appeared, to form described image thus by enabling described laminate layers generate trace point.

In preferred embodiments, described identification certificate also comprises biometric identification indicia.

In preferred embodiments, described identification certificate also comprises and is embedded in described additional clause smart card module.

The present invention also provides a kind of laminated identification document, and described laminated identification document comprises: the first transparent polymer film a) comprising top surface and basal surface; B) the second transparent polymer film of top surface and basal surface is comprised; C) image receiving layer of described first film top surface is provided in; D) compatibility layer contacted with described second film top surface with described first film basal surface, described compatibility layer plays the effect described first film and described second film are fixed to one another.

The present invention also provides a kind of method for generation of laminated identification document, said method comprising the steps of: the first laminate layers and the second laminate layers a) are provided, described first laminate layers has front surface and rear surface, and described second laminate layers has front surface and rear surface; B) be adjacent to arrange compatibility layer, to bond them together thus between the rear surface of described second pressure layer.

Accompanying drawing explanation

Will clearer further aspects, features and advantages of the present invention with reference to the detailed description and the accompanying drawings below.

Fig. 1 .1 is the viewgraph of cross-section of the exemplary identification certificate comprising certificate core.

Fig. 1 .2 is the viewgraph of cross-section of the exemplary identification certificate comprising certificate core, and comprises the representative functions of various layer.

Described viewgraph of cross-section and function are only exemplary, and those skilled in the art will know that other use or combination.

Fig. 2 is the viewgraph of cross-section of the test structure from Fig. 1 simplification, and this test structure allows the functional of test compatibility layer of the invention process.

Certainly, accompanying drawing is non-essential to be provided in proportion, and emphasis point is be placed in diagram principle of the present invention on the contrary.In the accompanying drawings, identical label instruction identical element.

Detailed description of the invention

The present invention relates to the identification certificate that can produce optical recording image thereon.The device being used for producing these images comprises optical pickup apparatus, generate with in the recording areas of certificate drawn by the image encoder of data corresponding to visual image, control both optical pick-up identifying in certificate the laser intensity LD control unit recording trace point (pit).Described trace point is carved to be formed and identifies that in the nontransparent and/or reflectivity recording medium of the vision of certificate top layer, these trace points are aimed at the color dot be positioned at below top layer.Therefore, when trace point is formed, it allows the color dot of below to become visual, forms visual image thus in certificate.In common CMYK(HexachrometmPantone company), CMYKOG(OpaltonetmOpaltone company), in CMYKR ' G ' ' B ' printing system, color dot can be printed on below imaging layer as full frame point.MichaelAdam etc. in PrintingTechnology(printing technology, DelmarThomsonLearning2002) schematically illustrate polychrome printing in chapter 5.The whole disclosure of Adam etc. is incorporated herein by reference.

System controller determines whether renewable data are stored in the recording areas identifying certificate, and records visual image by control LD control unit.Visual trace point is formed the point of the matrix appearing below printing.Wherein form wavelength and the reflectivity change in the district of cicatrization point, and this district becomes to user as visual.Therefore, except numerical data, on the data logger face of ID card, can record with colorful visual any character and figure that external equipment specifies.

In addition, still do not may be used for carrying out digital record in a usual manner by image forming material (engaging (the land)) region that cicatrization point " pierces through ".Therefore, such as, photo or bar code or other biological information can carry out record with two kinds of visual colors (using long or large trace point) in same media, and (have used stock size record trace point) wherein and be printed with in the engaging zones around the region of color dot and be recorded in a digital manner redundantly.Even may read cicatrization point and they are recorded as data.

In addition, when recording medium is metallic (such as aluminium, copper or other conductor materials or semiconductor) material, the engaging zones of remaining image forming material forms antenna, and when by RF radiation detection, described antenna has specific electromagnetism signature.Electromagnetism signature is used in the manufacture of the UHF static RFID tags such as made by AveryDennison company or Omron company.By firing suitable pattern at conduction imaging layer laser, it is readable that information can be encoded as RF.This allows the triplex level redundancy of information in card structure: visual ID, optical memory and RFID.

In addition, LD control unit can be designed to the visual image reading RF information and the establishment of larger trace point.Such as, White LED light source have for the color detector of ink dot.This is except allowing typical 0 or 1 digital record, also allows OpaltoneCMYKR ' G ' B ' to print the record of multiple state 0-7 in situation.Wherein, 0 be M for not record, 1 be not C, 2,3 be Y etc.There is the loss that 3+ factor increase additional in the memory span of many ON-OFFs can be used for by using larger trace point to offset memory span.For in any situation of ID card, memory requirement is very little, and easily can adapt to the 0-1 recording method of routine.

In addition, the image of visual CMYK color can be had with the usual manner printing providing the static tay formed by losing lustre.Such as, the seal (stateseal) in state.R ' G ' B point scatters with still image, and can individualize with laser, to provide the mark of such as individual photograph composition.Can substitute RGB point with the color dot that only just can detect when being exposed to the radiation outside visible ray, described radiation such as exposes UV or the IR radiation of fluorescence or phosphorescence ink dot.Described fluorescence or phosphorescence ink dot are used as safety sign.Now, this card with point of safes can have personal security's mark.Such as, the individual capacity number of individual or bar code.Now, also safety label may individualized outside the venue by the mode similar with central issuance card.

When carving with laser, usually expecting that protection carving area is with anti-tamper, and ensureing that mark has long useful life.Therefore, expect laser to concentrate on lower face.The energy absorption explosive force of this process can very high (multiple watt/square micron).This high power may cause the delamination in the structure of laminate layers.Explosive material can deposit on the surface again, causes image deflects or sky line defect.Therefore, expect to use rigid material, this rigid material can resist the explosive force of laser engraving, still maintains the integrality of binding structure simultaneously.

The present invention uses compatible image forming material, and this material with lower-wattage density (being less than 1 watt/micron) by laser index carving, and can still have very high bonding strength.Therefore, by reducing laser-induced explosion power and increasing the bonding strength of compatibility (compatibilised) structure, can create firm (robust) can laser index carving ID card structure, this structure can not delamination or in undesirable region deposition materials again.

One or more compatibilized layer is used between the laminate layers in identification card structure.More specifically, this compatibilized layer can be partially or completely heat cured.Preferably, for environment and reasons in structure, this layer comprises water base and/or radiation curable material.

In identification card structure, the use of this one or more compatibilized layer minimizes or prevents the bending stress damaging card, and/or prevents the cracking of the card caused due to normal wear and tearing itself.These layers can replace die attach adhesives conventional in smart card, eject from card to prevent smart card module when bending.

One or more compatibilized layer overcomes and the problem using the dicyandiamide solution with aggressivity organic solvent to be associated, described aggressivity organic solvent causes crackle (crazing), and cause the formation of ftractureing in polymer film, and for being not desirably environment and work safety problem.

One or more compatibilized layer in identification card can provide such card, in the visible area of the described 400-800nm of being stuck in, there is the transparency and for optical maser wavelength, there is absorbability, to allow to be marked with transparent overlay or lamination type white or clean core with the multi-color marking of such as bar code, photo and the mark marking that comprises other biological or data.In addition, one or more compatibilized layer can provide such identification card, described identification card has the transparency or opacity or reflectivity and has absorbability for optical maser wavelength in the visible area of 400-800nm, to allow to be marked with the white of nontransparent or reflective coating or lamination or clean core with the multi-color marking of such as bar code, photo and the mark that comprises other biological or data.In addition, if recording medium is metallic layers, then this metallic layers does not disturb RF data to the transmission of the antenna of contactless card, and this metallic layers self can be used as the antenna tag in response to RF radiation with signature unique.

Alternatively, recording medium is nontransparent or the nontransparent layer of part, described layer can become transparent by being exposed to laser energy, such as: cause foam collapse to become solid projection layer when heated---the froth bed of such as crystal or semi-crystal or light scattering liquid crystal layer, once be exposed to laser or other radiation, described froth bed becomes transparent.

Recording medium can also be holographic metallic layer, and imaging operation causes discontinuous in this metallic layers, and does not interfere RF data to the transmission of non-contact card antenna.Holographic material can have track to help guide and be similar to the LD Writing/Reading controlling mechanism that CD or DVD writes material.

Be used in here, term identification certificate and ID certificate intention comprise all types of identification certificate.In addition, be used in here, term certificate, card, badge and voucher can be used interchangeably.In addition, identify that certificate and ID certificate are broadly defined as here to comprise, but be not limited to, certificate, disk, credit card, bank card, phonecard, passport, driver's license, network access card, employee's badge, mark, chain decorations (fob), debit card, safety card, visa, immigration document, country ID card, citizen blocks, social insurance card and badge, certificate, identification card or certificate, voter's registration card, police ID card, arrival and departure card, security clearance badge and card, gun licensing, badge, gift token or card, member card or badge, label (tag), CD, DVD and such as knob (knob), keyboard, the consumer products of electronic building brick etc., or can recorded information, any other suitable item of image and/or other data or object, described information, image and/or other data can be designated the individual or brand identity that need specific level security and tamper-resistance properties, function and/or object or other entities are associated.

In addition, be used in here, mark includes, but not limited to information, decoration and any other purposes, and for described purposes, mark can be prepared in original, the part of object or be placed on this object under end-state.

Although the present invention is mainly used in secure ED token part and card, but additionally can be used in product label, the packing of product, business card, bag, icon, map, label etc., particularly be used in the article comprising laminate layers or top laminate layers (over-laminate) structure.Therefore, term " identification certificate " is here broadly defined as and comprises these labels, label, packaging, card etc.

As used herein, thermosets or polymer are the plastic materials chemical reaction by heat, radiation or catalyst standing or stood such as to be cross-linked being formed solid.Once this material have passed through its reaction, it can not get back to its original state, and can not flow when heating again.The chemical reaction that heat cure reaction can be hot means, radiation, catalyst or other means cause or cross-linking reaction.Pure thermosets is generally rigidity, but caoutchouc elasticity hot solids is also known.

Here, of the present invention many in one of in, developed a kind of compatible material system, described compatible material system comprises and retains flexible thermosets; This material is flexible and has enough thermosetting, with the heat resistanceheat resistant delamination when the various film used in marking structure and marker material provide bonding.After heat lamination, use the marking structure of compatible material system of the present invention to have very strong drag to delamination, and introduce impact strength for structure.

Be used in here, compatible (compatible) of term means the not conflict that works together.Details about compatilizer (compatibilizer) technique and material can at the book PolymericCompatibilizers of Datta etc., the use of UseandBenefitsinPolymerBlends(Its Compatibilizing Technology in blend polymer and benefit) find in (Hanser publishes and establishes, 1996).The whole disclosure of Data etc. is incorporated herein by reference.

As in laminate layers of the present invention the compatibility layer that uses can have one or more functions, such as, for the adhesive (adhesive) that layer is combined, be used for allowing for the ink of ornamental or Deta bearer object (such as biological data) or coloured coating (photo, bar code, fingerprint) excellent bonds is to the dyestuff of layer above or below and pigment carrier, be used for allowing ink and coloured coating excellent bonds to the security dyestuff of layer above or below and pigment (such as holography, pearly-lustre and metallic pigments) carrier, impact modified coating, print surface levelling agent when high-resolution printing usually can not be carried out on a rough surface, surface tension modifier, to allow polymer or layer of ink good contact each other, and as the acceptor coating for receiving mark.

Use compatibility layer in the present invention by intaglio printing, elasticity printing, serigraphy, duplicating based on liquid and solid-state ink powder, ink-jet and be applied to coating or mark, and extruded polymer or heat fusing thing can be applied to.The impact of delamination of being heated is much smaller because of its main thermoset nature for the laminate layers made with compatibility layer of the present invention.The laminate layers made with these materials performance in industrial ISO test is good.

One aspect of the present invention relates to the method being produced identification certificate by following steps: provide the first laminate layers, the second laminate layers and compatibility layer, and in described compatibility layer mode betwixt, they are laminated together subsequently.

Another aspect of the present invention relates to the method producing Intelligent Recognition card, comprises the following steps:

There is provided the first laminate layers and the second laminate layers, described first laminate layers has front surface and rear surface, and described second laminate layers has front surface and rear surface;

Adhesive is disposed adjacent with the rear surface of described first laminate layers;

Compatibility layer is disposed adjacent with the rear surface of described second laminate layers;

The core with top surface and basal surface is provided;

First laminate layers, adhesive phase, core, compatibility layer and the second laminate layers described in lamination, to form a structure;

A part for this structure of machined; And

The part be machined in this structure provides integrated circuit modules, and this integrated circuit modules provides the functional of at least some smart card.

Another aspect of the invention comprises a kind of identification certificate, and described identification certificate comprises:

First transparent polymer film, such as PET(PET) film, comprise top surface and basal surface;

Second transparent polymer film, such as PET film, comprise top surface and basal surface;

Be provided in the image receiving layer on described first film top surface;

The compatibility layer contacted with described second film top surface with described first film basal surface, described compatibility layer plays the effect described first film and described second film are fixed to one another.

Aforementioned structure can be made up of following middle at least one and himself or any combination each other: polymer, synthesis or non-synthetic paper, polyolefin, fill the polyolefin of silica, polyvinyl chloride, Merlon, the Polyesterterephthalate (polyesterterpthalate) of amorphous and two axle orientations and polyester naphthalate (polyesternapthanate), glycol-modified polyester, styrene, high impact polystyrene, acrylonitrile styrene butadiene, acrylic acid, polyketone, cellulose esters, polysulfones, polyamide, Merlon.Described polymer can be porous or non-porous synthetic material.

Another aspect of the invention provides a kind of method using compatibility layer of the present invention to make contactless smart identification certificate.The method comprises:

There is provided the carrier layer at least comprising antenna and electronic circuit, wherein said carrier comprises at least one permeable (permeable) region;

Described carrier layer is arranged between the first contact layer and the second contact layer, and subsequently

By heat and pressure at least one described first contact layer and the second contact layer are fixed to described carrier layer, with make one of described first contact layer and the second contact layer at least partially in a described permeable zone migration to described carrier layer; And

On the first and second contact layers, provide the first and second laminate layers at least respectively, in wherein said layer is one of at least compatibility layer.

For purpose of explanation, chapters and sections below will in general manner with reference to contact intelligent card (be sometimes called as the intelligent ID of contact interchangeably or identify certificate, or intelligent ID or identify certificate) launch.

Preferred contact Smart Logo comprises (fused) of certificate core and fusion or fixing (secured) polymer laminate layer, is one of at least wherein compatibility layer or laminate layers.The identification certificate of multilayer is equipped with integrated circuit to provide process and/or memory storage.But should recognize, the present invention is not limited to this.In fact, as skilled in the art will be aware of, inventive technology can be applied to other the structures a lot of formed in many different ways.Such as, non-contacting smart card module can suitably be encapsulated, and wherein such encapsulation is positioned in the chamber formed in multilayer certificate structure of the present invention.

Fig. 1 is the viewgraph of cross-section of the identification certificate according to one aspect of the invention.This mark (ID) certificate is used as the basis of Intelligent Recognition certificate.Mark (i.e. " information ") can be provided (such as serigraphy, hectographic printing, intaglio printing, hot transfer printing, is provided by laser ink-jet printing, laser engraving etc.) in core or tectal front surface and/or rear surface.Such as, described information can comprise variable information, and described variable information is the exclusive information (such as name, birthday, age, sex, body weight, address, biological information, photo and/or signature etc.) of card holder.Described information can also comprise so-called " fixing " information.Fix information is generally considered to be and keeps those constant information between different cards, safety Design of such as body release information, stamped signature and/or some types etc.Extra information, such as optically-variable element (opticalvariabledevice), may be provided in each layer of this structure.Other security features that Intelligent Recognition certificate can present alternatively comprise such as afterimage, micro-printing, ultraviolet or infrared image, biological information etc.Printing receiving body (such as image receiving layer) can be provided alternatively to help core for we or laminate layers receives the information of printing or transfer printing (such as better, see patent document and U.S. Patent No. 6,066, the D2T2 receiving body discussed in 594, this United States Patent (USP) is incorporated herein by reference).

Exist and much can be used in identification additional clause material of the present invention, for example, referring to Fig. 1, core material can comprise the synthetic (such as TESLIN) of porous, other synthetic materials, polymer, compound and/or polyolefin.TESLIN is the synthetic paper that a kind of PPG Industries Inc. sells, and can provide by opening, and wherein obtains multiple core from often opening TESLIN.

Porous material and non-porous materials can be used.Laminate layers (sometimes referred to as " top laminate layers (overlaminate) ") can include, but is not limited to film and slab products.The laminate layers that can use together with at least some embodiment of the present invention comprises those laminate layers comprising the compatible oxidant layer of polymer that can play the effect of adhesive, substantial transparent and/or substantial transparent, or has the polymer of substantial transparent and/or the adhesive of substantial transparent those laminate layers as a part (such as extruding feature) for its structure.In some embodiments of the present invention, term " laminate layers " can comprise laminate layers and adhesive phase (layer 8 and 9 of such as Fig. 1).The embodiment of available laminate layers comprises polyester, Merlon, polystyrene, cellulose ester, polyolefin, polysulfones or polyamide etc.Laminate layers can also use the polymer of amorphous or two axle orientations to make.Laminate layers can comprise multiple independent laminate layers, such as boundary layer and/or rete.

With reference to Fig. 1, layer 24 and other layers indicate core copolymer layer, and these can be formed by any polymer, such as polyester, polystyrene, cellulose ester, polyolefin, polysulfones or polyimides.The polymer of amorphous or two axle orientations can be used.But preferred polymers used herein is Merlon, PET and PVC.Polymer 24 can be coloured, such as, be white, to help to emphasize provided mark.Alternatively, compatibility layer 23 and 25 can be white (see embodiment 4 herein).

A kind of preferred realization adopts Merlon, polyester or PVC as overlie polymer, and the acrylate copolymer adopting UV to solidify is as compatilizer.Certainly, other materials can be used substitute.If adhesive phase comprises polyurethane, a kind of generally based on the chemicals of isocyanates, then various monomer and different reactants and additive can be used to the synthesis of the polymeric material with desirable properties, character such as flexibility, toughness, durability, viscosity and the UV stability of described expectation.In addition, the character of expectation can be realized at each layer of different urethanes of application.

This antenna/chip structure preferably arranges or is embedded in two cores between---layer 20-24 of Fig. 1---.Wherein, 20 and 24 is used the ramie cotton fabric (see embodiment 3 herein) that compatilizer 21 and 23 composition is saturated.

water base and the multi-functional compatibility material (compatibilizingmaterial) of UV-curable

The character of compatilizer used herein (compatibiliser) can by being customized in conjunction with following reagent:

C1-soft, some flexible polymers compositions

The polymers compositions of the rigidity that C2-is hard

C3-radiation curing agent (UV, visible ray, infrared ray, electron beam, microwave)

C4-chemical reactivity reagent or sensitizer

C5-heat reactivity reagent

C6-other control ink or the rheological stability of coating and the additive of transferring properties

Described compatilizer can be based on solvent, form based on the composition of water, hot melt (hotmelt) or radiation-hardenable.Can the composition of UV and visible light curable be preferred, because their commercially rapid curings on obtainable device.

The U.S. Patent No. 6,890,625 of authorizing Sigel describes typically for UV and the radiation curable formulation of hard surface coating.But similar composition can be formulated into soft.

The clad compositions of the UV-curable adopted herein comprises the component of one or more of UV-curable, monomer or oligomer (comprising ethylene linkage unsaturated) typically, and one or more delustering agents (flattingagents).Described composition can also comprise one or more of aqueous solvent and/or organic solvent, reactive diluent, UV light trigger, solidification conditioning agent (curealteringagent) and other selectable components.

the monomer of UV-curable

Anyly suitable can form coating (coatinglayer) when being applied to surface and the monomer solidified by UV or oligomer can be used as compatible reagent (compatabilisingagent) of the present invention.These monomers and oligomer are known in those skilled in the art.In one embodiment, described oligomer is at room temperature liquid, highly branched, and have multiple (methyl) acrylate functionalities.As used in this article, term " (methyl) acrylate " and variant thereof refer to acrylate, methacrylate and composition thereof.Embodiment comprises polyester (methyl) esters of acrylic acid, polyurethane (methyl) esters of acrylic acid, polyester-acrylic ammonia ester class, acrylate epoxy resin, polyepoxide compounds and composition thereof.They can also comprise mercaptan-alkene (thiol-ene) chemicals of acrylate or mixture and thiol-ene chemicals.In one embodiment, described acrylic acid ammonia ester class is derived from giving the aliphatic diisocyanate class of crosslink density in proper range and glass transition temperature for compatilizer.

In one embodiment, described resin structure comprises one or more of vulcabond and/or isocyanurate structure, PEPA and comprises the polyester of hydroxyl and acryloyl group degree of functionality.

c3-UV light trigger.Thermal initiator and solidification conditioning agent (CureAlteringAgents) (" gloss controlling agent (Gloss controllingAgents) ")

Light trigger can comprise the cationic photoinitiator of benzophenone initator, phosphinoxides, acetophenone derivs and such as triarylsulfonium salt and aryl salt (aryliodoniumsalts).In one embodiment, described light trigger is water miscible.Embodiment comprises benzophenone; 4-methyl benzophenone; Benzyl dimethyl ketal; Diethoxy acetophenone; Styrax ethers; Thioxanthene ketone; 1-hydroxy cyclohexyl phenylketone (Irgacure184 from CibaCorp obtains); 2-hydroxy-2-methyl-1-phenol-propyl-1-ketone; 4-(2-hydroxyl-oxethyl) phenyl-(2-hydroxy-2-methyl propyl group) ketone; TMDPO; Two (2,6-Dimethoxybenzoyl)-2,4,4-trimethylpentylphosphine oxide; 2,2-dimethoxy-2-phenyl acetophenone; 2-benzyl-2-N, N-dimethylamino-1-(4-morphlinophenyl)-1-butanone; 2-methyl isophthalic acid-[4-(methyl mercapto) phenyl]-2-morpholino third-1-ketone.

In one embodiment, described light trigger is benzophenone, separately or combine with other light triggers, light activating agent and/or sensitising agent.In another embodiment, be exposed to heat but not be exposed to light and produce the radical initiator (" thermal initiator ") of free radical, for example, various peroxide initiator, can by separately or combine with light trigger and adopt.These thermal initiators are known in those skilled in the art.In this case, the combination of heat or heat and UV irradiation can be used in first group of (firstset) polymerizing condition.

Can adopted commercially available light trigger comprise Darocur1173(2-hydroxy-2-methyl-1-phenol-propyl-1-ketone), Irgacure184(1-hydroxy cyclohexyl phenylketone), 2-hydroxy-2-methyl-1-phenyl-1-the ketone of Darocure4265(50% and 50% 2, 4, 6-trimethyl benzoyl diphenyl base phosphine oxide), Irgacure907(2-methyl isophthalic acid-[4-(methyl mercapto) phenyl]-2-morpholino third-1-ketone), two (2 of Irgacure1700(25%, 6-Dimethoxybenzoyl)-2, 4,-4-trimethylpentylphosphine oxide and 75% 2-hydroxy-2-methyl-1-phenyl-propyl-1-ketone), benzophenone, Irgacure819(BAPO phenyl two (2, 4, 6-trimethylbenzoyl)-phosphine oxide), Lucrin(MAPO diphenyl (2, 4, 6-trimethylbenzoyl)-phosphine oxide) and Irgacure651(α, alpha, alpha-dimethyl oxygen base-α-phenyl acetophenone), each in them is commercial can be obtained from CibaGeigy.The initator of other thioxanthones (thixanthone) compound race, such as ITX and CTX, can be used alone or combine with above-mentioned initator.

c-5 reactive diluent (ReactiveDiluents)

The embodiment of suitable reactive diluent comprises the material of propylene acidifying, such as (methyl) acrylic acid, (methyl) propylene isodecyl ester, N-vinyl formamide, (methyl) acrylic acid isoborneol (isobomyl) ester, (methyl) acrylic acid tetraethylene-glycol ester, (methyl) acrylic acid tripropylene glycol ester, two (methyl) propylene hexylene glycol ester, Ethoxylated bisphenol-A two (methyl) acrylate, ethoxylation two (methyl) acrylic acid DOPCP, propoxylation two (methyl) acrylic acid DOPCP, ethoxylation two (methyl) acrylic acid tripropylene glycol ester, glycerol propoxylate three (methyl) acrylate, three (2-ethoxy) isocyanuric acid three (methyl) acrylate, pentaerythrite three (methyl) acrylate, pentaerythrite four (methyl) acrylate, dihydroxy methylpropane three (methyl) acrylate dipentaerythritol caprolactone acrylate (dimethylolpropanetri (meth) acrylatedipentaerythritolcaprolactoneacrylate), hydroxyl caprolactone acrylate monohydroxy five (methyl) acrylate (hydroxycaprolactoneacrylatemonohydroxypenta (meth) acrylate), trimethylolpropane and three (methyl) acrylate and their ethoxylation and propenoxylated analog.

Ink connecting material/extender composition is known in those skilled in the art.In one embodiment, described compatibility layer is included in polyvinyl acetate base ester (the polvinylacetate)/polyvinyl chloride copolymer in suitable organic solvent (such as Slink0122, FMGroupInc.).Vinyl chloride/acetic acid vinyl ester resin the class of other hydroxyl modifications also can be used.Described compatibility layer can comprise esters of acrylic acid or derivatives thereof, and other comprise the bright system (varnishsystems) of the combination of esters of acrylic acid and/or its derivative and polyvinylidene chloride (polyvinylidinechloride) and/or polyvinylidene fluoride (polyvinylidinefluoride).

The resin forming compatibility layer is not limited especially, and polytype resin known in the art, such as resin glue can be used.The embodiment of the representational resin glue be listed can be the acrylic resin based on methyl polymethylacrylic acid, the resin (such as polystyrene etc.) of styrene-based, based on the resin (such as polyvinyl chloride etc.) of vinyl chloride, based on the resin (such as polyvinylidene chloride etc.) of vinylidene chloride, based on the resin (such as polyethylene terephthalate etc.) of polyester, based on cellulosic resin (such as cellulose acetate etc.), based on the resin (such as polyvinyl butyral resin etc.) of vinyl acetal, based on the resin of epoxy, based on the resin of acid amides, based on the resin of carbamate, based on the resin of melamine, based on the resin of alkyd, based on the resin of phenol, based on the resin of fluorine, based on the resin of silicon, pla-pcl, Merlon, polyurethane, polyvinyl alcohol, casein, gelatin etc.In addition, the resin that can be hardened by ionising radiation or heat can be used with the form of combination, and described resin is ionising radiation hardening resin or thermosetting resin such as.

In one embodiment, described reactive diluent is number-average molecular weight is the simple function of about 226 to about 2000 and polyfunctional esters of acrylic acid.Embodiment comprises the Tetraethylene glycol diacrylate that molecular weight is about 302, number-average molecular weight is Ethoxylated bisphenol-A two propylene (from the available SR602 of SartomerCompany) of about 776, the trihydroxy ethyl isocyanuric acid triacrylate (from the available SR368 of Sartomer) of molecular weight about 423, number-average molecular weight be about 296 trimethylolpropane triacrylate (from the available SR351 of Sartomer) and number-average molecular weight be that the ethoxylated trimethylolpropane triacrylate class of from about 400 to about 2000 is (from the available SR454 of SartomerCompany, SR499, SR502, SR9035 and SR415 and from available Photomer4155 and Photomer4158 of HenkelCorporation).

c5-chemosetting conditioning agent

Such reagent comprises the reagent that can promote or suppress to solidify.If described reagent promotes solidification, so when standing first group of (firstset) polymerizing condition, the UV-curable component comprised in the region (regions) of these reagent will with speed solidification faster.If described examination suppresses solidification, so when standing first group of polymerizing condition, the UV-curable component comprised in the region of these reagent will not exclusively be solidified or solidify with slower speed.Solidification not only can be promoted by solidification conditioning agent, can also be promoted by the light trigger of variable concentrations or type.

Sensitising agent and accelerator can include but not limited to ITX(isopropyl thioxanthone, Aceto) and CTX(clopenthixal ketone), quinones (such as camphorquinone, Michler'sKetone(4, two (dimethylamino) benzophenone of 4'-), thioxanthones, benzanthrone, triphenylbenzene ethyl ketone and Fluorenone (each in them all can obtain from Aldrich), dimethylethanolamine, methyl diethanolamine, triethanolamine, DMPT(N, N-dimethyl-p-toluidine), MHPT(N-[2-hydroxyethyl]-N-methyl-para-toluidine), ODAB(octyl group-p-N, N-dimethylaminobenzoic acid ester) and EDAB(ethyl-p-N, N-dimethylaminobenzoic acid ester), TPO, each in them of BAPO(all obtains from CibaGeigy is commercial).

Free radical inhibitors can include but not limited to N-nitroso-N-Phenylhydroxylamine, ammonium salt, three [N-nitroso-N-Phenylhydroxylamines], the hydroquinones of aluminium salt, mequinol MEHQ, quinhydrones and replacement, pyrogaelol, phenthazine and 4-ethylcatechol.UV absorbent comprises hydroxy-phenyl benzotriazole.

Additional light trigger and solidification conditioning agent are authorizing the U.S. Patent number 6,130 of the people such as Ukon, and be described in 270, the disclosure of described patent is incorporated herein by reference.

c5-reactive explosive

Reactive explosive comprises amino-compound or isocyanates (isiocyanetes), diisocyanates.Usually end-blocking (blocked) form is preferred, because lamination treatment has hot step, described hot step can make isocyanates remove end-blocking, and allow its formed in the crosslinked formula of urethane and urea with amino, amide groups and hydroxyl reaction, described urethane and urea are cross-linked the flexibility increasing this formula.Preferred isocyanates (isicyanate) is DesmodurDA(Bayer).

c6-delustering agent

Various delustering agent additive becomes known for adjustment coated glossy level.The embodiment of delustering agent comprises silica in small, broken bits and organic granular in small, broken bits, such as PergopakM-3.The embodiment of suitable delustering agent at U.S. Patent number 3,943,080,3,948,839 and 4,263, be described in 051, the disclosure of described patent is incorporated herein by reference.

c6-selectable components

Described clad compositions also can comprise the reagent that flowing additive (flowadditives), heat stabilizer, light stabilizer, dyestuff, pigment, optical brightener, surfactant, plasticizer, defoamer, hard particle, metallic particles and other those skilled in the art understand.

Metallic and/or the particle of polymerization, hard particle and coloured particle also can be included.Hard particle includes, but not limited to aluminium oxide, quartz, carborundum, bead and nano particle.When on the outer surface being used in the in such as Fig. 1 the 7th layer, this wear-resisting filler is also for compatilizer coating provides the resistance to marring of enhancing.

Embodiment

Made test card according to Fig. 2 with the PVC core of white (layer 20), described PVC core flat stamping has the standard industry UV vinyl flat stamping tusche from GansInkCo..This ink known for described core gives good viscosity and be cover layer (layer 10) give difference viscosity.The cover layer of PVC, polyester (PET) or Merlon all demonstrates almost does not have viscosity to UV tusche.Take advantage of the mistake size card of 12 centimetres to be made as 25 centimetres and there is the band flat stamping UV black that 25 centimetres are taken advantage of 7.5 centimetres, peel off and shock-testing to allow carrying out 90 degree.All structures are all that to follow 30 mils (mil) of iso standard thick.

Lamination

Laminate layers is a kind of manufacture in use three kinds of different laminations: heating platen lamination, hot roll lamination and radiation lamination.The condition quoted from is typical, and recognizes that other conditions can provide more excellent result.

All card structures are all set to provide 30+/-3 mil (gross thickness of 0.001 ").Follow ISO process and carry out 90 degree of stripping tests as the quick screening to Structural Integrity.Extra ISO integraty test always conforms to peel test results.

Lamination 1

Heating platen lamination: the steel plate of this chrome polish single, at 150 degrees Celsius, heating in 13 minutes, afterwards 25 degrees Celsius of coolings in 13 minutes.

Lamination 2

Hot roll lamination condition: Polaroid ID roll laminator, model 0927

Lamination 3

Check material by cold nonimpact printer (nip), compatilizer is uncured simultaneously, radiation curing afterwards: UV mercury lamp 300 watts/inch, speed 61-63 feet per minute clock, 3 times.

Lamination 4

Followed by lamination 2 after lamination 3.

embodiment 1

UV102(FM group), concentration is 100%, the vinyl acrylate copolymer (hard material) of the UV activation of configuration is used as compatilizer (Fig. 2, layer 11).Layer 12 is with the block flat stamping 100% density GansUV tusche of at least 1 " x3 " on core 20, to allow to peel off test.At UV black with do not print on white core and checked stripping.After the exposure of UV light, material is frangible.When with the clean PVC cover layer without coating in condition lamination 1 laminated time, for ISO90 degree peel off test between layer 10 and 20, there is no viscosity.

The all stripping data quoted from herein are according to this test.These tests become polyester (PET) to cover layer and Merlon (PC) repeats, and it comes to the same thing.

Layer	Composition
		10	Cover layer (PVC or polyester (PET) or Merlon)
11	Compatilizer UV102
		12	100% black UV ink (is covered with
20	Core (PVC, PET or PC)
		26	Cover layer (PVC or polyester (PET) or Merlon)

embodiment 2

UV103(FM group), the vinyl acrylate copolymer (soft material) that concentration is 100%, the UV of configuration activates, is used as compatilizer (Fig. 2, layer 11).After the exposure of UV light, material is frangible.When condition lamination 1 laminated, between layer #10-#20, there is no viscosity.

Layer	Composition
		10	Cover layer (PVC or polyester (PET) or Merlon)
11	Compatilizer UV103
		12	100% black UV ink (is covered with
20	Core (PVC, PET or PC)
		26	Cover layer (PVC or polyester (PET) or Merlon)

embodiment 3

By UV102(FM group), concentration is the vinyl acrylate copolymer (hard material) of the UV activation of 50%, with UV103(FM group), concentration is that the mixture that the vinyl acrylate copolymer (soft material) of the UV activation of 50% forms is used as compatilizer (Fig. 2, layer 11).This material is called as UV104-5050

After the exposure of UV light, material defines strong film.When at once using 1.8 mil PVC as layer 10 in condition lamination 1 laminated time, on white (10 to 20) and UV black layer 12, between layer 10 and 20, there is the viscosity of 90 degree, be 1.9 Newton/millimeter, be roughly 4 times (0.45 Newton/millimeter) of the requirement of ISO bank card.Impact is more than 40 millimeters/newton.

Layer	Composition
		10	Cover layer (PVC or polyester (PET) or Merlon)
11	Compatilizer UV104-5050
		12	100% black UV ink (is covered with
20	Core (PVC, PET or PC)
		26	Cover layer (PVC or polyester (PET) or Merlon)

embodiment 3.A

The structure identical with embodiment 3, but be laminated for 1 time at condition lamination.After 24 hours store, on white or UV black, having the viscosity of 90 degree between layer 10 and 20, be 0.5 Newton/millimeter (it is 0.45 Newton/millimeter that ISO bank card requires), but chain type heterogeneous peels off (zippeel).This may be the cause due to Post RDBMS technique.

embodiment 3.B

The structure identical with embodiment 3, but the curing agent (C5) adding extra 5%.On white or UV black, having the viscosity of 90 degree between layer 10 and 20, is 2.4 Newton/millimeter, more than 5 times of ISO bank card requirement (0.45 Newton/millimeter).Due to combination UV solidification and heat curing process, achieve high viscosity.

embodiment 3C

After the exposure of UV light, material defines strong film.When at once using 1.8 mil PVC as layer 10 in condition lamination 4 laminated time, on white (10 to 20) and UV black layer 12, between layer 10 and 20, there is the viscosity of 90 degree, be 3.5 Newton/millimeter, be roughly 4 times of ISO bank card requirement (0.45 Newton/millimeter).Impact is more than 40 millimeters/newton.After this demonstrating UV cooling layer pressure, the combination of heat lamination improves peel strength.

embodiment 4

The titanium dioxide of 40% is added to embodiment 3, UV104-5050(55% as Chinese white), also have the extra light trigger from C3, to help to solidify completely the nontransparent ink redying look.This ink is screen printed as layer 10 by the sieve of 305 microns.When with 1.8 mil PVC in condition lamination 1 laminated time, on white or UV black, between layer 10 and 20, have the viscosity of 90 degree, be 0.9 Newton/millimeter, be roughly 2 times of ISO bank card requirement (0.45 Newton/millimeter).

Layer

Composition

10	Cover layer (PVC or polyester (PET) or Merlon)
		11	Compatilizer UV104-5050+40% titanium dioxide+from the light trigger of C3
12	100% black UV ink (is covered with
		20	Core (PVC, PET or PC)

embodiment 5

Wink8600(FM group) be water base part heat-curable urethane dispersion.Use the Wink8600 of 100% concentration as compatilizer, Fig. 2, layer 11.Material forms film.When using 1.8 mil PVC as layer 10 in condition lamination 1 laminated time, on white (10 to 26) and UV black, between layer 10 and 20, have the viscosity of 90 degree, be 1.9 Newton/millimeter, be roughly 4 times of ISO bank card requirement (0.45 Newton/millimeter).Impact is more than 40 millimeters/newton.

Layer	Composition
		10	Cover layer (PVC or polyester (PET) or Merlon)
11	Compatilizer Wink8600
		12	100% black UV ink (is covered with
20	Core (PVC, PET or PC)
		26	Cover layer (PVC or polyester (PET) or Merlon)

embodiment 5.A

Identical with embodiment 5, just compatilizer is the Wink8600(FM group of 95%) and 5% curing agent.This thing is called as W8600T.When using 1.8 mil PVC as layer 10 in condition lamination 1 laminated time, on white (10 to 26) and UV black, between layer 10 and 20, have the viscosity of 90 degree, be 2.3 Newton/millimeter, be roughly 5 times of ISO bank card requirement (0.45 Newton/millimeter).Viscosity adds due to heat curing process.

embodiment 6

Identical with embodiment 3, just layer 10 is polyester (PETHostaphan, MitsubishiCorp) of 1.8 mils.When condition lamination 1 laminated, on white (10 to 26) and UV black, have the viscosity of 90 degree between layer 10 and 20, it can not delamination, or can not there is irregular film tear in PET.

Layer	Composition
		10	Cover layer 1.8 mil PET Hostaphan
11	Compatilizer UV104-5050
		12	100% black UV ink (is covered with
20	Core (PVC, PET or PC)

26	Cover layer 1.8 mil PET Hostaphan

embodiment 7

Structure identical with embodiment 6, is only the use of lamination 2 condition.On white or UV black, between layer 10 and 20, there is the viscosity of 90 degree, be 1.9 Newton/millimeter, be roughly 2 times of ISO bank card requirement (0.45 Newton/millimeter).This may be due to lamination 2 very short heating cycle, and may be able to optimize.

embodiment 8

Structure identical with embodiment 6, is only the use of lamination 3 condition.On white or UV black, between layer 10 and 20, there is the viscosity of 90 degree, be 1.9 Newton/millimeter, be roughly 2 times of ISO bank card requirement (0.45 Newton/millimeter).This may be the disappearance due to lamination 3 heating cycle, and may be able to be optimized better by extra or different initators.

embodiment 9.A

holographic foil---comparing embodiment

Structure identical with embodiment 3, just layer 12/20 is rigid white PVC and CFC(mono-Chicago, Illinois) laminate layers of rainbow holography aluminium foil that makes.When the printing acceptor based on unknown solvent is on layer 12 top, between layer 12 and 20,90 degree are made to peel off unsuccessfully with low-down peel strength.

Before stripping, embodiment 9A is placed in an and then RF card, and described RF card is general will by Card Reader in the distance from card reader 2-3 inch.Until this card is placed in when locating from card reader 0.5 inch, just Card Reader.This shows, the metal forming on the whole surface of card may affect readability due to the conductibility of paper tinsel.

Layer	Composition
		10	Cover layer 1.8 mil PVC
11	Compatilizer UV104-5050
		12	Rainbow holography aluminium foil
20	Core (PVC)
		26	Cover layer 1.8 mil PVC

embodiment 9.B

Holographic pigment

Wink8220H3(FM group), the water base part thermosetting urethane card compatilizer of 97% concentration and the easy miscible agent suspension of 3% holographic pigment water (10% pigment solids) (be similar to and authorizing the U.S. Patent No. 5,624 of Miekka, the pigment described in 076) are used as ink, Fig. 2, layer 12.This material forms film.Using 1.8 mil PVC as layer 10.When condition lamination 1 laminated, on white (10 to 20) and UV black, between layer 10 and 20, there is the viscosity of 90 degree, be 0.9 Newton/millimeter, be roughly 2 times (0.45 Newton/millimeter) of the requirement of ISO bank card.Impact is more than 40 millimeters/newton.

Before stripping, embodiment 9B is placed in an and then RF chip card, and described RF card is general will by Card Reader in the distance from card reader 2-3 inch.As gone out, it continues readable.This shows, the metallic holographic pigment on the whole surface of card can not affect readability because ink does not have conductibility.

Layer	Composition
		10	Cover layer 1.8 mil PVC
11	Compatilizer Wink8220-+3% holographic pigment
		12	100% black UV ink (being covered with)
20	Core (PVC)
		26	Cover layer 1.8 mil PVC

embodiment 9.C

This sample is identical with embodiment 9A, and just layer 20 is white PVC, and wherein on this white PVC, screen printing is brushed with magenta (magenta) ink 19.Employ IXLA100+Nd:YAG(neodymium: Yttrium-Aluminium-Garnet) laser, the light of 1064 nanometers, the laser instrument that power is 10 watts.Power is measured as 0.25 watt/square micron by Ophir laser power detection device (model #150C-A-.3-Y).LD control unit can make laser instrument get the bid indentation point at rainbow holography paper tinsel acceptor layer 12 with female face photograph image.The face of the magenta of display layer 19 is formed on hologram layer with the high-resolution being greater than 1200dpi.Otherwise, hologram layer 12 is unaffected, and this jig has the physical property similar with embodiment 9A.

Layer	Composition
		10	Cover layer (PVC or polyester (PET) or Merlon)
11	Compatilizer UV104-5050
		12	Rainbow holography aluminium foil
19	Wink861RRT compatilizer magenta Water-based screen ink
		20	Core (PVC)
26	Cover layer (PVC or polyester (PET) or Merlon)

embodiment 9.D

This sample is identical with embodiment 9B, and just layer 11 is the water-based ink WinkSRZ12R2 of non-holographic, a kind of water base metal magenta colorant.This ink is screen printed on white PVC.Employ described IXLA laser instrument to come with female face photograph image at aluminium acceptor layer acceptance of the bid indentation point.The face of magenta is formed in aluminium reflectivity layer of ink with the high-resolution being greater than 1200dpi.Otherwise, aluminium lamination 12 is unaffected, and this jig has the physical property similar with embodiment 9B.

Layer	Composition
		10	Cover layer 1.8 mil PVC
11	Compatilizer Wink SRZ12R2
		12	Core PVC
20	Core PVC
		26	Cover layer 1.8 mil PVC

embodiment 9.E

the polychrome printing of hologram transfer paper tinsel

Structure identical with embodiment 3, just layer 26 is the laminate layers with the rigid white PVC of CMY printing points and registration mark and the rainbow holography aluminium stamping systems of CrownRollLeaf manufacture.Adhesive with the removal of solvents from stamping systems, and is substituted by the layer of the water base compatibility layer of Wink861RT, the water base compatibility layer of described Wink861RT by #4 wire-wound rod apply and dried.Described paper tinsel is in turn laminated on the white PVC of color point printing, and this supporting body is divested and opens subsequently.This leaves the holographic foil on colored point.This subsequently with the coated PVC cover layer lamination of Wink861RT.Although be similar to structure 9A, this structure has the height being similar to embodiment 9B and binds peel strength.

Layer	Composition
		10	Cover layer (PVC)
11	Compatilizer Wink861RT
		12	Rainbow holography aluminium foil
13	Compatilizer Wink861RT
		19	The colour dot lattice of RGB printing
20	Core PVC
		26	Cover layer (PVC)

This structure is carved with Ixla laser device laser, to manifest one 3 look RGB images relative to metallic holographic background.Because disappearance video camera or other feedbacks allow laser image to the suitable optical alignment of RGB colour dot lattice, this color aims at deviation (off) slightly.

embodiment 9.F

Identical with embodiment 9E, just in order to black K color, laser power is adjusted to 0.7 watt/square micron.Define RGBK image.

embodiment 9.G

Identical with embodiment 9F, just laser imaging, not only to remove the metal level on RGB dot matrix, also removes the metal level appearing the non-imaged areas (joint) of white card bottom of and then described point.Relative to the white background of deviation slightly, define full RGBK image.

embodiment 9.G

Identical with embodiment 9D, just layer 12 is WinkSRZ12T printing, and described WinkSRZ12T printing is printed dot matrix with the RGB of layer 19 and aimed at, and only covers the point with metal level thus.This subsequently with compatibilized layer 11 cover layer 12 lamination.This similar, in embodiment 9B, just can carry out the high-contrast marking of silver in white background, and without the need to carrying out laser ablation to a region for surrounding as in embodiment 9G.Layer 20/19/12 can use the flat stamping machine being equipped with coated of online flexographic printing to print in not expensive mode.

Layer	Composition
		10	Cover layer (PVC)
11	Compatilizer Wink861RT
		12	WINK SRZ12T imaging
19	The colour dot lattice of RGB printing
		20	Core PVC
26	Cover layer (PVC)

embodiment 10

multiple can the transparent composition of marking

The water base pressure type laminate layers of Wink3300BC, a kind of with the small-molecular-weight water based transparent vinyl dispersion of phosphate charrant additive (phosphatecharrantadditive) as D2T2 acceptor compatible with laser, by the layer 11 that 305 orders (US, the U.S.) tulle printing is in Fig. 2.Layer 10 is omitted, and this structure is in lamination 1 condition laminated, and just the heat time reduces to 5 minutes, to reduce any possibility of premature decomposition and to increase throughput.This is stuck in the printing of D2T2CMYK bar on Fargo and Datacard machine, and produces high contrast print and readable bar code.This is stuck in low-power with various laser device laser marking: NdYAG, diode pumping NdVanadate and carbon dioxide laser, and all laser instruments all produce the black designation of high-contrast.

Layer	Composition
		11	The water base pressure type laminate layers of D2T2 compatilizer Wink3300BC
20	Core (PVC, PET or PC)
		26	Cover layer 1.8 mil PVC

embodiment 10.B

Blanket layer pressure type card, has clean tectal white PVC.This is stuck in low-power with various laser device laser marking: NdYAG, diode pumping vanadic acid neodymium (NdVanadate) and carbon dioxide laser, and all laser instruments all produce low contrast mark.

Layer	Composition
		11	PVC cover layer
20	Core (PVC)
		26	Cover layer 1.8 mil PVC

embodiment 11

polycarbonate compositions---comparative example

Make the card of 100% Merlon, it comprises white core and clean cover layer, and 170 degrees Celsius of laminations 20 minutes.This card is exposed to the plasticizer DINP following ISO322-2002, and the INCITS following specification 5.6 carries out crooked test.Card is broken into two halves after 24 hours.

Layer	Composition
		11	Cover layer 1.8 mil PVC
20	Core PC
		26	Cover layer 1.8 mil PVC

embodiment 11B

the printable durability polycarbonate compositions of D2T2

Identical with embodiment 11, just before being laminated, polycarbonate cap layer is with WINK8207G, and---a kind of water base part heat-curable urethane dispersion---is coated, and---a kind of low-molecular-weight water based transparent vinyl dispersion as D2T2 acceptor---is coated subsequently using Wink335Presslam.Card is exposed to the plasticizer DINP following ISO322-2002 subsequently, and the INCITS following specification 5.6 carries out crooked test.Different from embodiment 11, card is after 24 hours without any cracking.This shows, adds chemical durability to this card structure.This is stuck in the printing of D2T2CMYK bar on Fargo and Datacard machine, and produces high contrast print and readable bar code.

embodiment 11C

laser can marking and the printable durability polycarbonate compositions of D2T2

Identical with embodiment 11B, just before being laminated, polycarbonate cap layer is that Bayer can the Merlon of laser treatment level.Card is exposed to the plasticizer DINP following ISO322-2002 subsequently, and the INCITS following specification 5.6 carries out crooked test.Different from embodiment 11, card is after 24 hours without any cracking.This shows, adds chemical durability to this card structure.This is stuck in the printing of D2T2CMYK bar on Fargo and Datacard machine, and produces high contrast print and readable bar code.This card is the process of available NdYag laser device laser, and produces high-contrast black designation.

embodiment 12

The combination of UV exposure and heat lamination

The degree of laminate layers transparency such as can be determined by the information that core layer comprises, the particular color used and/or security features.Any laminate layers can use conventional laminating technology to realize to the lamination of any other material layer, and such technique is that in the production of articles field such as identifying certificate, technical staff is known.Certainly, type and the structure of laminate layers described herein only provide by way of example, one of skill in the art will appreciate that can use much dissimilar laminate layers according to the present invention.

The material making laminate layers can be transparent, but needs not be transparent.Laminate layers also comprises security laminate layers; such as there is the transparent laminating layer material of private security technical characteristic and technique; it is protected, and valuable certificate is not forged, data change, photo are replaced, copied (comprising color printing), and any by using general obtainable material and technology-imitation.The size of ID certificate can be different according to specific design requirement.Such as, for identifying that the International Organization for Standardization the applied specification of certificate can specify required size.In the size of regulation, there is the flexibility of some sizes.In one implementation, we provide the core comprising the 4-20 mil degree of depth, have the compatilizer of the 0.2-7 mil degree of depth, and scope is at the overlaminate layer of 1-15 mil.

In some implementations, we overleaf laminate layers top surface provide matte finish (mattefinish).If provided with roll form, then this matte finish helps this laminate layers of feeding.Matte finish also provides sense of touch security features, as examiner can feel the texture (matte finish) of card, to determine whether this card is legal.

Further, although we describe some materials and size for our contactless smart identification certificate, the present invention should not be limited to this.Really, the present invention includes the contactless smart identification certificate more with different size and material.

This may be favourable, namely the blank certificate of gained is provided subsequently to multiple credential issuance station (OTC station) at the coated image receiving material of centralization production mechanism, at described credential issuance station, variable data are applied to the image receiving layer of described identification certificate.

After image-receptive layer by layer printing information (if provided, otherwise on pet layer printing after), alternatively this image receiving layer at least partially on enclose protective layer (not shown).This protective layer plays the relatively fragile image receiving layer of protection from the effect damaged, and prevents information (such as hot dye transfer) from revealing from image receiving layer.The material being suitable for being formed such protective layer is known to the skilled in dye diffusion thermal transfer print field; and the material of any routine can be used; as long as they have enough transparencys and have enough viscosity to specific image receiving layer, they contact with described image receiving layer and/or stop dyestuff to be revealed from this layer.But in order to consistent with the theme of this aspect of the present invention, if you are using, we preferably apply the transparent protection laminate layers based on PET.

Protective layer can provide extra security and/or feature alternatively for permit identification part.Such as; protective layer can comprise low sticky polymer layer, ink variable alternatively, variable information, with ink print infrared or ultraviolet is readable but under normal white light sightless image, with the image of fluorescence or phosphorescence ink print, cohesive failure ink; or any other obtainable security features; described security features protection certificate is from distorting or forging, and sacrificial protective layer protection does not identify the ability of certificate opposing wearing and tearing and protection element.

(not shown) at least one embodiment, laminate layers is formed bag (pouch), and core layer slips in this bag.Use bag, such as the method for heating, pressure, adhesive etc. can be used for core layer to be attached to pocket type laminate layers.One of skill in the art will appreciate that the structure much becoming known for lamination can use with configuration together with the present invention.

Inventor believes, relates to expansion (intumesceance) mechanism in the laser index carving of material.Therefore, requirement is, needs enough heat absorptions to make material expansion or to burn (char).This is realized by absorbing laser energy.For for endergonic polymeric material, it must have light spectrum absorption in optical maser wavelength region.The much different laser instrument of various wavelength and power can be obtained.For the most generally diode pumping vanadic acid neodymium of laser index carving, neodymium YAG and carbon dioxide laser.

Also be obtainable in point other wavelength absorption at the material that visible area is transparent, such as infrared transparent dyestuff, manufacture as Epolin company those.

the non-IR dyes of coating is loaded with for solvent

PEOLIGHT(Epolin company)

Narrow-band absorption agent

4037743 platinum dithiolenes (dithiolene)

3036773 nickel dithiolenes

3211785 nickel dithiolenes

3442817 nickel dithiolenes

3443868 nickel dithiolenes

3116892 nickel dithiolenes

2067905 3 ammoniums (trisamminium)

2063906 3 ammoniums

2177976 3 ammoniums

2062977 3 ammoniums

2066978 3 ammoniums

2057990 3 ammoniums

2189990 3 ammoniums

2180991 3 ammoniums

2164993 3 ammoniums

11511070 four ammoniums (tetrakisamminium)

11171071 four ammoniums

11781073 four ammoniums

1097 nickel dithiolenes

3045

Broadband

Absorbent

1175948 4 ammoniums

1125950 4 ammoniums

1130960 4 ammoniums

Other materials of such as cyanine (cyanine) because they in YAG and vanadate lasers be suitable for the absorbability in Jin IR district and especially useful.

Known polymer decomposes and burns under heat load.For low-molecular weight polymer especially like this, for this reason, there is a lot of stabilization additives.See such as R.Gachter and H.Muller at PlasticAdditives(plastic additive, editor Hauser/MacMillan, New York, 1988,754) reviewofDecompositionMechanismsandThermalStabilizers(quoted in decomposes mechanism and heat stabilizer review).Typically, heat stabilizer is used to allow these materials to be processed.

The present inventor believes, applies and without undergoing the non-stabilizing material of extreme heat stress or partially stabilized material by being used as ink or coating under the low temperature compared with its decomposition point, can by laser index carving.These materials are together with burning organizator and the adjustment optical maser wavelength absorbent to laser absorption wavelength, or the rudimentary wide spectral absorbent of picture carbon black, can the transparent composition of marking by likely preparing laser.

Except identification card market, laser the composition of marking also can should be applicable to the requirement of card structure and be tested by various ISO.The one considered is needed to be certain expansion structure foam.This may be desirably, and be that tactile feature given by ID card because mark will be made to be raised for it, it may can replace some embossed features blocked.But inflation (gassing) is not always controlled, and can pollute described marking image.Due to the abrasion of the image of rising, the tactile feature on surface can also stand larger wearing and tearing.Therefore, that expects to make without the need to inflation high-contrast can laser labelling.Therefore, people will want to control described inflation independent of burning.

If multiple wavelength can marking laser can marking material with accept D2T2 and print and the combination of materials of ink jet printing, then to produce desirably multiple can marking material.

Various in water base, based on solvent and radiation-cured form, wherein add with broad base and selective radiation absorbent the low molecular weight monomers, oligomer and the polymer that burn organizator diode laser pump vanadic acid neodymium, neodymium (Nd) Yag laser instrument and carbon dioxide laser can be used to realize having the laser index carving of high-contrast.

In the embodiment detailed above, the particular combination of element and feature is only exemplary; These instructions and other exchanges of instruct in the document and the document that comprises by reference and alternatively also to be taken explicitly into account to.

Concept of the present invention can be used in Intelligent Recognition certificate, and described identification certificate comprises:

Comprise the core layer of first surface and second surface, described core layer comprises the first material;

The polymeric layer of the first substantial transparent, be disposed adjacent the first surface in described core layer and be attached to described first surface regularly, to form the certificate structure with the first and second surfaces, the polymer of the substantial transparent of wherein said ground floor comprises substantially different from described first material materials;

Wherein, the second surface of the first surface of described core layer, the first surface of described certificate structure, described certificate structure, and at least one in the second surface of described core layer carries the mark of at least one printing thereon, and the polymeric layer of described substantial transparent comprises compatibility layer.

Alternatively, at least one in the first surface of described core layer and described compatibility layer comprises mark thereon.Described mark comprises biological information, and the photo of such as personage represents, the fingerprint of people or the marking.

Described core layer can be following at least one: porous synthetic material, polymer, synthesis or non-synthetic paper, polyolefin, fills the polyolefin of silica, polyvinyl chloride, Merlon, the Polyesterterephthalate (polyesterterpthalate) of amorphous and two axle orientations and polyester naphthalate (polyesternapthanate), glycol-modified polyester, styrene, high impact polystyrene, acrylonitrile styrene butadiene, acrylic acid, polyketone, cellulose esters, polysulfones, polyamide, Merlon.

Described ground floor can for being disposed adjacent the polymer of the substantial transparent on the first surface of described core layer, comprise following at least one: non-porous synthetic material, polymer, synthesis or non-synthetic paper, polyolefin, fill the polyolefin of silica, polyvinyl chloride, Merlon, the Polyesterterephthalate (polyesterterpthalate) of amorphous and two axle orientations and polyester naphthalate (polyesternapthanate), glycol-modified polyester, styrene, high impact polystyrene, acrylonitrile styrene butadiene, acrylic acid, polyketone, cellulose esters, polysulfones, polyamide, Merlon.

Described core layer can be porous TESLIN or the LUPO synthesis of polyolefins of micropore.

Described core layer can be non-porous or PVC, PET of porous or Merlon.

Described core layer can be paper or plate, such as passport paper or cover paper.

The first polymeric layer being disposed adjacent the described substantial transparent on described core layer first surface comprises front surface and rear surface, described front surface is the surface be disposed adjacent on the first surface of described core, and wherein said front surface and/or rear surface there is in several ways (such as laser, ink-jet, dye diffusion thermal transfer, thermoprint, embossing, intaglio printing, flat stamping, flexible printing, serigraphy, wet ink duplicate, solid ink duplicate) can the acceptor coating of marking.

Described identification certificate can by milling (bemilled) to form the chamber for holding contact smart card modules.

The present invention can use in the certificate comprising smart card module.Such module can be received smart card module by milling one chamber in identification certificate and generate.Such certificate comprises core interlayer (sandwich) structure of at least laminate layers certificate, and wherein said laminate layers comprises the material substantially different from described certificate core, and described method comprises:

In laminate layers, provide the first cutting, to create rough upper chambers, described rough upper chambers comprises the first opening;

There is provided the second cutting to create lower chamber, described lower chamber extends through described laminate layers and enters into described certificate core, described lower chamber and described rough upper chambers are shown greatly centered by common axis, the opening of wherein said lower chamber is less than the opening of described rough upper chambers relatively, causes a shelf structure (shelf) in described laminate layers; And

There is provided the 3rd cutting around described rough upper chambers, to create final upper chambers, described final upper chambers has the opening larger than the opening of described rough upper chambers, and described final upper chambers is shown greatly centered by described common axis.Described first, second, and third cutting is like this cutting, though the part of the smart card module that must be accepted substantially float on chamber, described upper and lower one of at least in.

The present invention can be used to produce non-contacting Intelligent Recognition card.Such identification card is produced by following steps:

There is provided the carrier layer at least comprising transceiver and electronic circuit, wherein said carrier comprises at least one permeable region;

By at least one in heat, pressure and radiation, described first contact layer and the second contact layer are fixed to described carrier layer, make one of described first contact layer and the second contact layer at least partially in a described permeable zone migration to described carrier layer; And

At least on the first and second contact layers, provide laminate layers.

Claims

1. the individualized of a safety lamination type RF of laser index carving can identify certificate, for recording scheduled recognition image and electromagnetism are signed thereon, described laminated identification document has multiple laminate layers, described identification certificate comprises compatibility layer, described compatibility layer is incorporated into adjoining laminate layers on each surface of described compatibility layer, at least one in described laminate layers is image-receptive lamination layer, described compatibility layer comprises image forming material at least one surface, described image forming material can utilize laser emission by laser index carving in the power density being less than 1 watt/micron, to form described predetermined recognition image, and keep being combined with the stickiness of described multiple adjacent layer, wherein cover the described adjacent image comprising the described surface of described image forming material to receive laminate layers be nontransparent or the nontransparent conductor of part or semi-conducting material, and be described laser emission absorbent and after being revealed in described laser emission, described image-receptive lamination layer becomes transparent and described laser emission forms the antenna with the readable electromagnetism signature of RF on described image-receptive lamination layer.

2. identify certificate as claimed in claim 1, wherein said compatibility layer comprises polymer, and described polymer is selected from by being the group that partially or completely heat cured water based curable polymers or radiation-curable polymer or its mixture form.

3. identify certificate as claimed in claim 1, wherein said compatibility layer has the transparency at the visible area of 400-800 nanometer, and has absorbability to optical maser wavelength.

4. identify certificate as claimed in claim 1, wherein said compatibility layer has highly reflective at the visible area of 400-800 nanometer, and has absorbability to optical maser wavelength.

5. identify certificate as claimed in claim 1, wherein said compatibility layer can be nontransparent or the nontransparent recording medium of part.

6., for the lamination type RF of predetermined recognition image and electromagnetism signature record security personalization is thereon identified a certificate, comprising:

Core laminate, described core laminate has upper surface and lower surface, at least one surface in described upper surface and lower surface is printed lattice diagram, wherein said point has the non-imaged part adjacent with described point, wherein said core lamination comprises at least one compatibility layer, at least one compatibility layer described is incorporated into adjoining laminate layers on each surface of described compatibility layer, described compatibility layer comprises image forming material at least one surface, described image forming material can utilize laser emission by laser index carving in the power density being less than 1 watt/micron, identification marking image is formed while being combined with the stickiness of described adjoining laminate layers in maintenance, wherein covering the described adjoining laminate layers comprising the surface of described image forming material is transparent for described laser emission, and

Nontransparent or the reflective image of at least one vision of conductor or semi-conducting material receives laminate layers, nontransparent or the reflective image of described vision receives laminate layers and laser emission can be utilized to produce trace point, and the nontransparent or reflective image of described vision receives laminate layers and is attached to and printedly has at least one surface described of described lattice diagram and cover printed at least one surface described having described lattice diagram;

Wherein once utilize laser emission to make described image-receptive lamination layer produce trace point, the multiple parts being printed on the described lattice diagram on described core laminate are appeared, to form described predetermined recognition image thus and the remaining engaging zones of described lamination forms the antenna with the readable electromagnetism signature of RF.

7. identify certificate as claimed in claim 6, wherein said compatibility layer comprises polymer, and described polymer is selected from by being the group that partially or completely heat cured water based curable polymers or radiation-curable polymer or its mixture form.

8. identify certificate as claimed in claim 6, wherein said compatibility layer has the transparency at the visible area of 400-800 nanometer, and has absorbability to laser emission.

9. identify certificate as claimed in claim 6, wherein said compatibility layer has highly reflective at the visible area of 400-800 nanometer, and has absorbability to laser emission.

10. identify certificate as claimed in claim 6, wherein said compatibility layer can be nontransparent or the nontransparent recording medium of part.

11. identify certificate as claimed in claim 6, and wherein said lattice diagram comprises the point of multiple different colours.

12. identify certificate as claimed in claim 6, and wherein said lattice diagram is printed as full frame point.

13. identify certificate as claimed in claim 6, and wherein said nontransparent or reflective laminate layer comprises printing another identification marking thereon.

14. identify certificate as claimed in claim 6, are also included in the nontransparent or compatibilized layer between reflective laminate layer and described core laminate of described vision, to be bonded to each other by these laminate layers thus.

15. identify certificate as claimed in claim 6, also comprise biometric identification indicia.

16. identify certificate as claimed in claim 6, also comprise the smart card module be embedded in described antenna communication in described certificate.

17. identify certificate as claimed in claim 6, also comprise other laminate layers covering described image-receptive lamination layer, other wherein such laminate layers are transparent for laser emission and can be watched by predetermined recognition image described in other laminate layers described.