JP5853884B2 - Hot-dip galvanized steel sheet and manufacturing method thereof - Google Patents

Description

  The present invention relates to a high-strength hot-dip galvanized steel sheet excellent in workability suitable for use as a steel sheet for automobiles and a method for producing the same.

  In recent years, improving the fuel efficiency of automobiles has become an important issue from the viewpoint of conservation of the global environment. For this reason, efforts are being made to reduce the thickness by increasing the strength of the vehicle body material and to improve the fuel efficiency by reducing the weight of the vehicle body itself. Steel sheets that are formed by pressing or bending like automobile parts are required to have formability that can withstand processing while maintaining high strength. In particular, in actual press molding, there is a strong demand for processing without necking, and uniform elongation (hereinafter referred to as UEL) is important. For improving UEL, it is known that the use of transformation induced plasticity (hereinafter referred to as TRIP) effect due to retained austenite is effective. For example, Patent Document 1 discloses a technique related to TRIP steel. . Such a so-called low-alloy TRIP steel is usually bainite transformed by annealing and holding in an overaged zone after cooling, and carbon (hereinafter referred to as C) is concentrated in austenite to stabilize austenite. And produced by a method of generating retained austenite. However, in the hot dip galvanized steel sheet, there is a problem that workability (ductility) is remarkably lowered because austenite is decomposed by immersion in the plating bath or heat treatment by alloying. On the other hand, Patent Document 2 discloses a technique that suppresses the decomposition of austenite and improves workability (ductility) by adding Mo. However, while austenite stabilizing elements such as Mo and Cr are effective in suppressing the decomposition of austenite, there is a problem that the amount of stable austenite decreases at the time before plating because it significantly hinders the progress of bainite transformation. In general, the two are in a trade-off relationship, and there is no technique for suppressing the decomposition of austenite without hindering the bainite transformation.

Japanese Patent Laid-Open No. 61-217529 JP 2011-17046 A

  The present invention advantageously solves the problems of the prior art described above, and is suitable as a material for automobile parts. High strength melting excellent in workability of tensile strength TS: 980 MPa or more, TS × UEL: 15000 MPa ·% or more It aims at providing a galvanized steel plate and its manufacturing method.

  In order to achieve the above-mentioned problems and to produce a high-strength hot-dip galvanized steel sheet having excellent workability, the present inventors have conducted extensive research from the viewpoint of the component composition and microstructure of the steel sheet. As a result, a predetermined amount of Sn is added. Has been found to be extremely effective in solving the above problems. That is, it was found that it is important to control the area ratio of bainitic ferrite, martensite and tempered martensite, and retained austenite within a predetermined range as a microstructure in steel having Sn and other specific component compositions. . As one embodiment of the manufacturing method, steel having Sn or other specific component composition is hot-rolled at a finish rolling temperature of Ar3 transformation point or higher, cooled, and then cold-rolled at 400 to 700 ° C. The cold-rolled steel sheet produced by applying the above-mentioned temperature is maintained at Ac3 transformation point −50 ° C. to 1000 ° C. for 10 s or more, then cooled to a cooling stop temperature of 150 to 550 ° C. at an average cooling rate of 5 ° C./s or more, and 350 to 550 ° C. It was found that a high-strength hot-dip galvanized steel sheet excellent in workability with TS of 980 MPa or more and TS × UEL of 15000 MPa ·% or more is obtained by holding for 10 to 1500 seconds at .

The present invention has been made based on such findings, and provides the following inventions.
(1) By mass%, C: 0.15 to 0.40%, Si: 0.5 to 3.0%, Al: 0.010 to 3.000%, Mn: 1.5 to 4.0% , P: 0.100% or less, S: 0.020% or less, Sn: 0.01 to 0.50%, with the balance being composed of Fe and inevitable impurities, and an area ratio of 3 High-strength melt with excellent workability having a microstructure containing 68% bainitic ferrite, martensite and tempered martensite with a total area ratio of 10 to 65%, and retained austenite with an area ratio of 5% or more Galvanized steel sheet.
(2) Further, in terms of mass%, Cr: 0.005 to 0.200%, Mo: 0.005 to 0.200%, V: 0.005 to 0.200%, Ni: 0.005 to 0.00. 200%, Cu: at least one element selected from 0.005 to 0.200%, and the total thereof is 0.200% or less, the high-strength molten zinc having excellent workability as described in (1) Plated steel sheet.
(3) Further described in (1) or (2) containing at least one element selected from Ti: 0.005 to 0.200% and Nb: 0.005 to 0.200% by mass%. High-strength hot-dip galvanized steel sheet with excellent workability.
(4) The high-strength hot-dip galvanized steel sheet excellent in workability according to any one of (1) to (3), further containing, by mass%, B: 0.0003 to 0.0050%.
(5) In addition, any one of (1) to (4) containing at least one element selected from Ca: 0.001 to 0.005% and REM: 0.001 to 0.005% by mass% High-strength hot-dip galvanized steel sheet with excellent workability as described in 1.
(6) The heat which winds at the temperature of 400-700 degreeC after the hot rolling completion | finish in the slab which has a component in any one of (1)-(5) after finishing rolling temperature at Ar3 transformation point or more. After performing a rolling step to obtain a hot-rolled sheet, the cold-rolled steel sheet produced by performing cold rolling is heated to Ac3 transformation point −50 ° C. to 1000 ° C. and held for 10 s or more, and then 5 ° C./s. After cooling to a cooling stop temperature of 150 to 550 ° C. at the above average cooling rate, holding at a temperature of 350 to 550 ° C. for 10 to 1500 s, and then applying hot dip galvanization, high strength melting with excellent workability Manufacturing method of galvanized steel sheet.
(7) In the method for producing a high-strength hot-dip galvanized steel sheet according to (6), a high-strength hot-dip galvanized steel sheet excellent in workability characterized by further subjecting it to an alloying treatment of galvanizing after hot-dip galvanizing Manufacturing method.

  In the present invention, the high-strength hot-dip galvanized steel sheet excellent in workability refers to a hot-dip galvanized steel sheet having a tensile strength TS of 980 MPa or more and TS × UEL: 15000 MPa ·% or more. The high-strength hot-dip galvanized steel sheet of the present invention includes a plated steel sheet (hereinafter sometimes referred to as GI) that is not subjected to alloying after the hot-dip galvanizing process, and a plated steel sheet (hereinafter referred to as GA) that is subjected to the alloying process. In some cases).

  According to the present invention, it is possible to obtain a high-strength hot-dip galvanized steel sheet excellent in workability, which is suitable as a material for automobile parts, TS: 980 MPa or more and TS × UEL: 15000 MPa ·% or more.

  Details of the present invention will be described below. Note that “%” representing the content of component elements means “% by mass” unless otherwise specified.

1) Component composition C: 0.15 to 0.40%
C is an element necessary for increasing TS by generating a low-temperature transformation phase such as martensite and tempered martensite. Further, it is an element effective for stabilizing austenite to generate retained austenite and improving the workability of steel. If the C content is less than 0.15%, the production of retained austenite becomes insufficient and it is difficult to obtain high workability. On the other hand, from the viewpoint of spot weldability, the C content is preferably low, and the upper limit is made 0.40%. Therefore, the C content is 0.15 to 0.40%, preferably 0.17 to 0.35%.

Si: 0.5 to 3.0%
Si is an element effective for improving the workability of steel by solid-solution strengthening steel to increase TS, or suppressing the formation of carbides to generate retained austenite. In order to obtain such an effect, the Si amount needs to be 0.5% or more. On the other hand, when it exceeds 3.0%, brittleness becomes remarkable, and surface properties and weldability are deteriorated. Therefore, the Si amount is 0.5 to 3.0%, preferably 0.5 to 2.5%, more preferably 0.8 to 2.0%.

Al: 0.010 to 3.000%
Al, like Si, is an element effective for improving the workability of steel by solid-solution strengthening steel to raise TS and suppressing the formation of carbides to produce retained austenite. It is also effective as a deoxidizer. In order to obtain such an effect, the Al amount needs to be 0.010% or more. On the other hand, if it exceeds 3.000%, austenitization becomes difficult, and a desired structure cannot be obtained after annealing. Therefore, the amount of Al is made 0.010 to 3.000%, preferably 0.010 to 2.000%, more preferably 0.010 to 1.000%.

Mn: 1.5-4.0%
Mn is an element that raises TS by solid-solution strengthening steel and raises TS, or promotes the generation of low-temperature transformation phases such as martensite and tempered martensite. In order to acquire such an effect, it is necessary to make Mn amount 1.5% or more. On the other hand, when the amount of Mn exceeds 4.0%, the increase of inclusions becomes remarkable, which causes the cleanliness of steel and the deterioration of workability. Therefore, the amount of Mn is 1.5 to 4.0%, preferably 1.8 to 3.5%.

Sn: 0.01 to 0.50%
Sn is an element that stabilizes austenite, suppresses its decomposition, and obtains retained austenite to raise UEL. In order to obtain such an effect, the Sn amount needs to be 0.01% or more. On the other hand, when the Sn content exceeds 0.50%, brittleness becomes remarkable. Therefore, the Sn content is 0.01 to 0.50%, preferably 0.02 to 0.25%.

P: 0.100% or less P degrades steel by grain boundary segregation and degrades weldability. Therefore, the amount is desirably reduced as much as possible. Therefore, the P content is 0.100% or less.

S: 0.020% or less S is present as inclusions such as MnS, and deteriorates weldability. Therefore, the amount is preferably reduced as much as possible. Therefore, the S amount is 0.020% or less.

  The balance is Fe and inevitable impurities, but one or more of the following elements can be appropriately contained as necessary.

Cr: 0.005 to 0.200%, Mo: 0.005 to 0.200%, V: 0.005 to 0.200%, Ni: 0.005 to 0.200%, Cu: 0.005 Contains at least one selected from 0.200%, and the total is 0.200% or less. Cr, Mo, V, Ni, and Cu generate low-temperature transformation phases such as martensite, and are effective in increasing strength. Element. In order to obtain such an effect, the content of each of at least one element selected from Cr, Mo, V, Ni, and Cu is preferably 0.005% or more. On the other hand, when the addition amount of these elements increases, the delay of the bainite transformation becomes remarkable, and the amount of retained austenite decreases and the workability decreases, so the upper limit of the total is made 0.200%. Therefore, the content of each of at least one element selected from Cr, Mo, V, Ni, and Cu is preferably 0.005 to 0.200% and a total of 0.200% or less. More preferably, the total content is 0.100% or less.

At least one type of Ti and Nb selected from Ti: 0.005 to 0.200% and Nb: 0.005 to 0.200% forms carbonitrides and increases the strength of the steel by precipitation strengthening. It is an effective element. In order to obtain such an effect, the content of each of Ti and Nb is preferably 0.005% or more. On the other hand, when the content of each of Ti and Nb exceeds 0.200%, the effect of increasing the strength is saturated and the UEL decreases. Therefore, the content is preferably 0.005 to 0.200%.

B: 0.0003 to 0.0050%
B is effective in suppressing the formation of ferrite from the austenite grain boundaries and generating a low-temperature transformation phase to increase the strength of the steel. In order to obtain such an effect, the B content is preferably 0.0003% or more. On the other hand, if it exceeds 0.0050%, the effect is saturated and the cost is increased. Therefore, the content is preferably 0.0003 to 0.0050%.

At least one type of Ca and REM selected from Ca: 0.001 to 0.005% and REM: 0.001 to 0.005% are both effective elements for improving workability by controlling the form of sulfide. It is. In order to obtain such an effect, the content of each of at least one element selected from Ca and REM is preferably 0.001% or more. On the other hand, if it exceeds 0.005%, the cleanliness of the steel is adversely affected and the properties may be deteriorated. Therefore, the content is preferably 0.001% to 0.005%.

  Even if N is contained as an inevitable impurity in an amount of 0.006% or less, there is no problem.

2) Microstructure bainitic ferrite: 3 to 68%
Bainitic ferrite produced by the bainite transformation is effective in concentrating C into austenite and obtaining retained austenite. In order to express such an effect, it is necessary to make bainitic ferrite 3% or more in area ratio. On the other hand, since the strength of bainitic ferrite itself is not so high, when the area ratio exceeds 68%, it becomes difficult to obtain 980 MPa or more in TS. Therefore, the area ratio of bainitic ferrite is set to 3 to 68%.

Total of martensite and tempered martensite: 10-65%
Martensite and tempered martensite are effective in raising TS. In addition, martensite (tempered martensite after annealing) generated when cooling is stopped at a temperature of 350 to 550 ° C. for 10 to 1500 seconds is the starting point of bainite transformation and promotes bainite transformation. It is effective in increasing the UEL by generating residual austenite by concentrating C in the austenite. In order to exhibit such an effect, the area ratio of martensite and tempered martensite needs to be 10% or more in total. On the other hand, when the area ratio exceeds 65%, the decrease in the amount of retained austenite generated becomes significant, and the UEL decreases. Therefore, the total area ratio of martensite and tempered martensite is 10 to 65%.

Residual austenite: 5% or more Residual austenite is effective in increasing UEL, and in order to sufficiently exhibit such an effect, it is necessary that the retained austenite be 5% or more in terms of area ratio. The upper limit is not particularly defined, but when manufactured within the scope of the present invention, the austenite that can remain stabilized is about 20% or less. Accordingly, the retained austenite is 5% or more in area ratio, preferably 8% or more.

In the present invention, bainitic ferrite, martensite, tempered martensite, and retained austenite may contain other phases (for example, polygonal ferrite and pearlite) as long as the above conditions are satisfied. However, from the viewpoint of TS and UEL, the total of other phases is preferably 20% or less.
Here, the area ratio of bainitic ferrite, martensite, and tempered martensite is the ratio of the area of each phase in the observed area, and the area ratio of bainitic ferrite, martensite, and tempered martensite is After polishing the plate thickness section of the steel plate, it was corroded with 3% nital, and the position of the plate thickness 1/4 was photographed with three fields of view at a magnification of 1500 times with SEM (scanning electron microscope), and from the obtained image data, Media Cybernetics The area ratio of each phase was determined using Image-Pro manufactured by the company, and the average area ratio of the three fields of view was defined as the area ratio of each phase. In the image data, bainitic ferrite exhibits a black color in the secondary electron image of the SEM and can be distinguished from other phases from its form. Both martensite and retained austenite are white in the secondary electron image of SEM. However, the area ratio of retained austenite can be obtained by the following method, so the area ratio of retained austenite is reduced from the area ratio of the entire white structure. The site area ratio is required. Tempered martensite is a white-colored structure in which clear carbide formation along the lath structure inside martensite is observed, and can be distinguished from other phases. The ratio of retained austenite is determined by using the Kα ray of Mo with an X-ray diffractometer on the surface polished by 0.1 mm by chemical polishing after the steel plate is polished to a thickness of 1/4. Measure the integrated intensity of the (200), (220), (311) planes and the (200), (211), (220) planes of bcc iron, and each surface of fcc iron in the integrated reflection intensity from each surface of bcc iron The intensity ratio of the integrated reflection intensity from was obtained, and this was defined as the area ratio of retained austenite.

3) Manufacturing conditions The high-strength hot-dip galvanized steel sheet of the present invention is cooled and wound at a temperature of 400 to 700 ° C. on the slab having the above component composition after finishing the hot rolling at a finish rolling temperature not lower than the Ar3 transformation point. After performing the hot rolling process to obtain a hot rolled sheet, the cold rolled steel sheet produced by further cold rolling is subjected to continuous annealing, heated to an Ac3 transformation point of −50 ° C. to 1000 ° C. and held for 10 s or more. After cooling to a cooling stop temperature of 150 to 550 ° C. at an average cooling rate of at least ° C./s, it can be produced by performing hot dip galvanizing treatment after holding at 350 to 550 ° C. for 10 to 1500 seconds.
This will be described in detail below.

When hot rolling is performed at a finish rolling temperature higher than the Ar3 transformation point and less than the hot rolling Ar3 transformation point, it tends to be a heterogeneous structure in which austenite and ferrite are mixed because of the ferrite formation region. Incurs a decline. Therefore, it is preferable to perform hot rolling at a finish rolling temperature of Ar3 transformation point or higher. The Ar3 transformation point was determined from the following formula.
Ar3 (° C.) = 868-396 × (% C) + 25 × (% Si) −68 × (% Mn)
In the formula,% C,% Si, and% Mn indicate the content (mass%) of each element.

When the coiling temperature at a temperature of 400 to 700 ° C. is higher than 700 ° C., the surface of the steel sheet is excessively oxidized, resulting in an increase in surface roughness and defects. On the other hand, when the coiling temperature is less than 400 ° C., the deterioration of the hot-rolled plate shape becomes remarkable. Therefore, the coiling temperature is preferably 400 ° C to 700 ° C, more preferably 560 to 670 ° C.

As a cold rolling cold rolling condition, it is preferable that the cold rolling reduction is 5% or more. Moreover, in order to reduce the rolling load at the time of cold rolling, you may give hot-rolled sheet annealing to the hot-rolled sheet after winding.

Ac3 transformation point −50 ° C. to 1000 ° C. Heated to 10 ° C. or more, and Ac3 transformation point−less than −50 ° C., austenite formation is insufficient, the amount of retained austenite finally obtained is lowered, and workability is lowered. To do. The upper limit is preferably 1000 ° C. or less from the viewpoint of productivity. The Ac3 transformation point was determined by the following formula.
Ac3 (° C.) = 910−203 × √ (% C) + 44.7 × (% Si) −30 × (% Mn) + 200 × (% Al)
In the formula,% C,% Si,% Mn, and% Al indicate the content (mass%) of each element.
When the holding time is less than 10 s, austenite is not sufficiently generated, the amount of retained austenite finally obtained is lowered, and workability is lowered. Accordingly, the holding time is 10 s or longer. The upper limit is not particularly specified, but is preferably about 1000 s or less from the viewpoint of manufacturability.

When the average cooling rate of 5 ° C./s or more is less than 5 ° C./s, ferrite and pearlite are excessively generated during cooling and TS is lowered. Therefore, the average cooling rate is 5 ° C./s or more.

Cooling stop temperature of 150 to 550 ° C. If the cooling stop temperature is less than 150 ° C., tempered martensite is excessively generated, the amount of retained austenite finally obtained is reduced, and workability is lowered. On the other hand, when the cooling stop temperature exceeds 550 ° C., the bainite transformation is delayed, so the amount of bainitic ferrite is reduced, C concentration in austenite is insufficient, and ferrite and pearlite are easily generated. The amount of retained austenite finally obtained is lowered, and the workability is lowered. Therefore, the cooling stop temperature is 150 to 550 ° C, preferably 200 to 500 ° C.

If the holding temperature of holding for 10 to 1500 s at a holding temperature of 350 to 550 ° C. is less than 350 ° C., the bainite transformation is delayed and the lower bainite is generated, so the amount of C enrichment to austenite is reduced and sufficient. Residual austenite cannot be obtained and workability is reduced. On the other hand, when the temperature exceeds 550 ° C., the bainite transformation is delayed, so the amount of bainitic ferrite produced is reduced, C concentration in austenite is insufficient, and ferrite and pearlite are easily produced. Thus, the amount of retained austenite obtained is reduced, and the workability is lowered. Therefore, the temperature is 350 to 550 ° C, preferably 370 to 500 ° C. Further, in order to obtain a desired holding temperature, reheating may be performed as necessary from the cooling stop temperature.
If the holding time is less than 10 s, bainite transformation does not occur sufficiently, the amount of bainitic ferrite produced decreases, and sufficient retained austenite cannot be obtained, so that workability is lowered. On the other hand, when the holding time exceeds 1500 s, the decomposition of austenite becomes remarkable and the workability deteriorates. Therefore, the holding time is 10 to 1500 s.

Hot-dip galvanizing treatment After the above-mentioned annealing, hot-dip galvanizing and further alloying treatment as necessary. The plating treatment is preferably performed by immersing the steel plate obtained as described above in a galvanizing bath at 440 ° C. or higher and 500 ° C. or lower, and then adjusting the plating adhesion amount by gas wiping or the like. The plating adhesion amount is preferably in the range of 20 to 60 g / m ² . Furthermore, when alloying galvanizing, it is preferable to alloy by maintaining in a temperature range of 460 ° C. or more and 580 ° C. or less for 1 second or more and 40 seconds or less. As the galvanizing bath, it is preferable to use a galvanizing bath having an Al content of 0.08 to 0.28 mass%.

  The steel sheet after being subjected to hot dip galvanizing treatment or further alloying treatment can be subjected to temper rolling for the purpose of shape correction, adjustment of surface roughness, and the like. Moreover, various coating processes, such as resin and oil-fat coating, can also be given.

  The conditions for other production methods are not particularly limited, but the following conditions are preferable.

  The slab is preferably produced by a continuous casting method in order to prevent macro segregation, but can also be produced by an ingot-making method or a thin slab casting method. To hot-roll the slab, the slab may be cooled to room temperature and then re-heated for hot rolling, or the slab may be charged in a heating furnace without being cooled to room temperature. Can also be done. Alternatively, an energy saving process in which hot rolling is performed immediately after performing a slight heat retention can also be applied. When heating a slab, it is preferable to heat to 1100 degreeC or more in order to dissolve a carbide | carbonized_material and to prevent the increase in rolling load. In order to prevent an increase in scale loss, the heating temperature of the slab is preferably 1300 ° C. or lower.

  When hot rolling a slab, the rough bar after rough rolling can be heated from the viewpoint of preventing troubles during rolling even if the heating temperature of the slab is lowered. Moreover, what is called a continuous rolling process which joins rough bars and performs finish rolling continuously can be applied. Further, in order to reduce the rolling load and make the shape and material uniform, it is preferable to perform lubrication rolling in which the friction coefficient is 0.10 to 0.25 in all passes or a part of the finish rolling.

  The steel sheet after winding is subjected to cold rolling, annealing, and hot dip galvanizing under the above conditions after removing the scale by pickling.

Steel having the composition shown in Table 1 was melted in a vacuum melting furnace and rolled into a steel slab (in Table 1, N is an unavoidable impurity). These steel slabs were heated to 1200 ° C., followed by rough rolling, finish rolling and winding to obtain hot rolled sheets having a sheet thickness of 2.3 mm. Subsequently, it cold-rolled to 1.4 mm, manufactured the cold-rolled steel plate, and used for the annealing. After annealing under the annealing conditions shown in Tables 2 and 3, hot dip galvanizing treatment was performed, and steel plate No. 1-28 were produced. A hot dip galvanized steel sheet (GI) is immersed in a plating bath at 460 ° C., formed with a coating amount of 35 to 45 g / m ² , and then cooled to room temperature at an average cooling rate of 10 ° C./second. did. Moreover, the alloyed hot-dip galvanized steel sheet (GA) was produced by performing alloying treatment at 550 ° C. after plating formation and cooling to room temperature at an average cooling rate of 10 ° C./second. And about the obtained hot-dip galvanized steel plate, a JIS No. 5 tensile test piece was extracted in a direction perpendicular to the rolling direction, and a tensile test was performed at a strain rate of 10 ⁻³ / sec. In addition, about the microstructure of each steel plate, the area ratio was calculated | required by the above-mentioned method.

  In addition, the plating property was evaluated by visually judging the appearance and the presence or absence of non-plating / defects.

  The results are shown in Tables 4 and 5.

  In the example of the present invention, TS was 980 MPa or more, TS × UEL was 15000 MPa ·% or more, and it was confirmed that the material had processability. Moreover, in the example of this invention, there is no non-plating and a defect and plating property is favorable.

  According to the present invention, it is possible to obtain a high-strength hot-dip galvanized steel sheet having excellent workability that is TS: 980 MPa or more and TS × UEL: 15000 MPa ·% or more. When the high-strength hot-dip galvanized steel sheet of the present invention is used for automotive parts, it contributes to reducing the weight of an automobile and greatly contributes to improving the performance of an automobile body.

Claims (7)

In mass%, C: 0.15 to 0.40%, Si: 0.5 to 3.0%, Al: 0.010 to 3.000%, Mn: 1.5 to 4.0%, P: 0.100% or less, S: 0.020% or less, Sn: 0.01 to 0.50%, with the balance being composed of Fe and inevitable impurities, and an area ratio of 3 to 68% TS: 980 MPa or more, TS × UEL: 15000 MPa · having a microstructure containing bainitic ferrite, martensite and tempered martensite with a total area ratio of 10 to 65%, and retained austenite with an area ratio of 5% or more % Hot dip galvanized steel sheet. TS represents tensile strength and UEL represents uniform elongation. Furthermore, in mass%, Cr: 0.005 to 0.200%, Mo: 0.005 to 0.200%, V: 0.005 to 0.200%, Ni: 0.005 to 0.200%, Cu: at least one element selected from 0.005 to 0.200%, and the total thereof is 0.200% or less. TS: 980 MPa or more, TS × UEL: 15000 MPa ·% according to claim 1 or more of hot-dip galvanized steel sheet. Furthermore, TS: 980 MPa or more according to claim 1 or 2, further comprising at least one element selected from Ti: 0.005 to 0.200% and Nb: 0.005 to 0.200% by mass%. TS × UEL: Hot-dip galvanized steel sheet of 15000 MPa ·% or more . Furthermore, TS: 980 MPa or more and TSxUEL: 15000 MPa *% or more hot-dip galvanized steel sheet in any one of Claims 1-3 which contain B: 0.0003-0.0050% by mass%. Furthermore, TS in any one of Claims 1-4 which contains at least 1 type of element chosen from Ca: 0.001-0.005% and REM: 0.001-0.005% by the mass%. A hot-dip galvanized steel sheet of 980 MPa or more and TS × UEL: 15000 MPa ·% or more . The slab having the component according to any one of claims 1 to 5 is subjected to a hot rolling step in which the finish rolling temperature is cooled at an Ar3 transformation point or higher after hot rolling is completed and wound at a temperature of 400 to 700 ° C. After forming into a rolled sheet, when the cold-rolled steel sheet produced by cold rolling is subjected to continuous annealing, it is heated to Ac3 transformation point -50 ° C to 1000 ° C and held for 10s or more, and then an average cooling rate of 5 ° C / s or more. After cooling to a cooling stop temperature of 150 to 550 ° C., holding at a temperature of 350 to 550 ° C. for 10 to 1500 s, and then performing hot dip galvanizing, bainitic ferrite with an area ratio of 3 to 68%, , Having a microstructure including martensite and tempered martensite with a total area ratio of 10 to 65% and residual austenite with an area ratio of 5% or more, TS: 980 MPa or more, TS × UEL Manufacturing method of 15,000 MPa ·% or more galvanized steel sheet. The method of manufacturing a molten zinc coated steel sheet according to claim 6, TS, characterized in that after galvanizing, further alloyed galvanized applied: 980 MPa or more, TS × UEL: 15000MPa ·% or more of the melting Manufacturing method of galvanized steel sheet.